Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)

The asymmetric unit of the title compound, (C(8)H(8)N(5))(2)[Ce(NO(3))(5)(H(2)O)(2)], contains one independent protonated 4-pyridyl­methyl­eneamino-1,2,4-triazole cation and half of a centrosymmetric [Ce(NO(3))(5)(H(2)O)(2)](2−) anion. The Ce atom coordinated by five NO(3) (−) anions and two water m...

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Detalles Bibliográficos
Autores principales: Sun, Qiaozhen, Zheng, Feng, Sun, Xiaodan, Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968024/
https://www.ncbi.nlm.nih.gov/pubmed/21581488
http://dx.doi.org/10.1107/S1600536808043109
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author Sun, Qiaozhen
Zheng, Feng
Sun, Xiaodan
Wang, Wei
author_facet Sun, Qiaozhen
Zheng, Feng
Sun, Xiaodan
Wang, Wei
author_sort Sun, Qiaozhen
collection PubMed
description The asymmetric unit of the title compound, (C(8)H(8)N(5))(2)[Ce(NO(3))(5)(H(2)O)(2)], contains one independent protonated 4-pyridyl­methyl­eneamino-1,2,4-triazole cation and half of a centrosymmetric [Ce(NO(3))(5)(H(2)O)(2)](2−) anion. The Ce atom coordinated by five NO(3) (−) anions and two water mol­ecules, exhibiting a distorted 10-coordination. In the crystal structure, inter­molecular O—H⋯N and N—H⋯O hydrogen bonds result in the formation of a supramolecular structure.
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spelling pubmed-29680242010-12-30 Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III) Sun, Qiaozhen Zheng, Feng Sun, Xiaodan Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(8)H(8)N(5))(2)[Ce(NO(3))(5)(H(2)O)(2)], contains one independent protonated 4-pyridyl­methyl­eneamino-1,2,4-triazole cation and half of a centrosymmetric [Ce(NO(3))(5)(H(2)O)(2)](2−) anion. The Ce atom coordinated by five NO(3) (−) anions and two water mol­ecules, exhibiting a distorted 10-coordination. In the crystal structure, inter­molecular O—H⋯N and N—H⋯O hydrogen bonds result in the formation of a supramolecular structure. International Union of Crystallography 2008-12-24 /pmc/articles/PMC2968024/ /pubmed/21581488 http://dx.doi.org/10.1107/S1600536808043109 Text en © Sun and Zheng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Qiaozhen
Zheng, Feng
Sun, Xiaodan
Wang, Wei
Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)
title Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)
title_full Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)
title_fullStr Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)
title_full_unstemmed Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)
title_short Bis{4-[(4H-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(III)
title_sort bis{4-[(4h-1,2,4-triazol-4-yl)iminomethyl]pyridinium} diaquapentanitratocerate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968024/
https://www.ncbi.nlm.nih.gov/pubmed/21581488
http://dx.doi.org/10.1107/S1600536808043109
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