2,3,5-Triphenyl­pyrazine

In the title mol­ecule, C(22)H(16)N(2), the pyrazine ring deviates very slightly from planarity [maximum deviation 0.044 (3) Å], tending towards a twist-boat conformation. The phenyl ring at position 3 makes dihedral angles of 64.0 (2) and 45.8 (2)°, respectively, with the phenyl rings at positions...

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Autores principales: Anuradha, N., Thiruvalluvar, A., Pandiarajan, K., Chitra, S., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968030/
https://www.ncbi.nlm.nih.gov/pubmed/21581569
http://dx.doi.org/10.1107/S1600536808041627
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author Anuradha, N.
Thiruvalluvar, A.
Pandiarajan, K.
Chitra, S.
Butcher, R. J.
author_facet Anuradha, N.
Thiruvalluvar, A.
Pandiarajan, K.
Chitra, S.
Butcher, R. J.
author_sort Anuradha, N.
collection PubMed
description In the title mol­ecule, C(22)H(16)N(2), the pyrazine ring deviates very slightly from planarity [maximum deviation 0.044 (3) Å], tending towards a twist-boat conformation. The phenyl ring at position 3 makes dihedral angles of 64.0 (2) and 45.8 (2)°, respectively, with the phenyl rings at positions 2 and 5. The dihedral angle between the phenyl rings at positions 2 and 5 is 49.7 (2)°. A C—H⋯π inter­action is found in the crystal structure, but no classical hydrogen bonds form.
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spelling pubmed-29680302010-12-30 2,3,5-Triphenyl­pyrazine Anuradha, N. Thiruvalluvar, A. Pandiarajan, K. Chitra, S. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(22)H(16)N(2), the pyrazine ring deviates very slightly from planarity [maximum deviation 0.044 (3) Å], tending towards a twist-boat conformation. The phenyl ring at position 3 makes dihedral angles of 64.0 (2) and 45.8 (2)°, respectively, with the phenyl rings at positions 2 and 5. The dihedral angle between the phenyl rings at positions 2 and 5 is 49.7 (2)°. A C—H⋯π inter­action is found in the crystal structure, but no classical hydrogen bonds form. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2968030/ /pubmed/21581569 http://dx.doi.org/10.1107/S1600536808041627 Text en © Anuradha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, N.
Thiruvalluvar, A.
Pandiarajan, K.
Chitra, S.
Butcher, R. J.
2,3,5-Triphenyl­pyrazine
title 2,3,5-Triphenyl­pyrazine
title_full 2,3,5-Triphenyl­pyrazine
title_fullStr 2,3,5-Triphenyl­pyrazine
title_full_unstemmed 2,3,5-Triphenyl­pyrazine
title_short 2,3,5-Triphenyl­pyrazine
title_sort 2,3,5-triphenyl­pyrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968030/
https://www.ncbi.nlm.nih.gov/pubmed/21581569
http://dx.doi.org/10.1107/S1600536808041627
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AT thiruvalluvara 235triphenylpyrazine
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AT chitras 235triphenylpyrazine
AT butcherrj 235triphenylpyrazine

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