1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride

The title N-heterocyclic carbene derivative, C(23)H(33)N(4) (+)·Cl(−), has been synthesized and characterized by elemental analysis, (1)H and (13)C NMR, IR spectroscopy and a single-crystal X-ray diffraction study. Ions of the title compound are linked by three C—H⋯Cl inter­actions. The seven-member...

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Detalles Bibliográficos
Autores principales: Arslan, Hakan, VanDerveer, Don, Gök, Yetkin, Özdemir, İsmail, Çetinkaya, Bekir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968033/
https://www.ncbi.nlm.nih.gov/pubmed/21581572
http://dx.doi.org/10.1107/S1600536808041603
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author Arslan, Hakan
VanDerveer, Don
Gök, Yetkin
Özdemir, İsmail
Çetinkaya, Bekir
author_facet Arslan, Hakan
VanDerveer, Don
Gök, Yetkin
Özdemir, İsmail
Çetinkaya, Bekir
author_sort Arslan, Hakan
collection PubMed
description The title N-heterocyclic carbene derivative, C(23)H(33)N(4) (+)·Cl(−), has been synthesized and characterized by elemental analysis, (1)H and (13)C NMR, IR spectroscopy and a single-crystal X-ray diffraction study. Ions of the title compound are linked by three C—H⋯Cl inter­actions. The seven-membered 1,3-diazepane ring has a form inter­mediate between twist-chair and twist-boat.
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spelling pubmed-29680332010-12-30 1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride Arslan, Hakan VanDerveer, Don Gök, Yetkin Özdemir, İsmail Çetinkaya, Bekir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title N-heterocyclic carbene derivative, C(23)H(33)N(4) (+)·Cl(−), has been synthesized and characterized by elemental analysis, (1)H and (13)C NMR, IR spectroscopy and a single-crystal X-ray diffraction study. Ions of the title compound are linked by three C—H⋯Cl inter­actions. The seven-membered 1,3-diazepane ring has a form inter­mediate between twist-chair and twist-boat. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2968033/ /pubmed/21581572 http://dx.doi.org/10.1107/S1600536808041603 Text en © Arslan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arslan, Hakan
VanDerveer, Don
Gök, Yetkin
Özdemir, İsmail
Çetinkaya, Bekir
1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride
title 1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride
title_full 1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride
title_fullStr 1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride
title_full_unstemmed 1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride
title_short 1,3-Bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1H-1,3-diazepan-2-ium chloride
title_sort 1,3-bis[4-(dimethyl­amino)benz­yl]-4,5,6,7-tetra­hydro-1h-1,3-diazepan-2-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968033/
https://www.ncbi.nlm.nih.gov/pubmed/21581572
http://dx.doi.org/10.1107/S1600536808041603
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AT gokyetkin 13bis4dimethylaminobenzyl4567tetrahydro1h13diazepan2iumchloride
AT ozdemirismail 13bis4dimethylaminobenzyl4567tetrahydro1h13diazepan2iumchloride
AT cetinkayabekir 13bis4dimethylaminobenzyl4567tetrahydro1h13diazepan2iumchloride

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