2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide

The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol­ecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of inter­molecular N—H⋯N hydrogen bonds and I⋯O inter­actions link neighbourin...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza, Maity, Annada C., Maity, Sibaprasad, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968040/
https://www.ncbi.nlm.nih.gov/pubmed/21581580
http://dx.doi.org/10.1107/S1600536808041950
Descripción
Sumario:The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol­ecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of inter­molecular N—H⋯N hydrogen bonds and I⋯O inter­actions link neighbouring mol­ecules into two different pairs of dimers, those involving N—H⋯N interactions having R (2) (2)(8) ring motifs. Short inter­molecular I⋯O [3.1458 (15) Å] and I⋯N [3.4834 (16) Å] contacts are present. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions [3.565 (2) and 3.629 (2) Å].

Ejemplares similares