2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide

The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol­ecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of inter­molecular N—H⋯N hydrogen bonds and I⋯O inter­actions link neighbourin...

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Autores principales: Fun, Hoong-Kun, Kia, Reza, Maity, Annada C., Maity, Sibaprasad, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968040/
https://www.ncbi.nlm.nih.gov/pubmed/21581580
http://dx.doi.org/10.1107/S1600536808041950
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author Fun, Hoong-Kun
Kia, Reza
Maity, Annada C.
Maity, Sibaprasad
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Kia, Reza
Maity, Annada C.
Maity, Sibaprasad
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol­ecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of inter­molecular N—H⋯N hydrogen bonds and I⋯O inter­actions link neighbouring mol­ecules into two different pairs of dimers, those involving N—H⋯N interactions having R (2) (2)(8) ring motifs. Short inter­molecular I⋯O [3.1458 (15) Å] and I⋯N [3.4834 (16) Å] contacts are present. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions [3.565 (2) and 3.629 (2) Å].
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spelling pubmed-29680402010-12-30 2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide Fun, Hoong-Kun Kia, Reza Maity, Annada C. Maity, Sibaprasad Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol­ecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of inter­molecular N—H⋯N hydrogen bonds and I⋯O inter­actions link neighbouring mol­ecules into two different pairs of dimers, those involving N—H⋯N interactions having R (2) (2)(8) ring motifs. Short inter­molecular I⋯O [3.1458 (15) Å] and I⋯N [3.4834 (16) Å] contacts are present. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions [3.565 (2) and 3.629 (2) Å]. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2968040/ /pubmed/21581580 http://dx.doi.org/10.1107/S1600536808041950 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
Maity, Annada C.
Maity, Sibaprasad
Goswami, Shyamaprosad
2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide
title 2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide
title_full 2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide
title_fullStr 2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide
title_full_unstemmed 2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide
title_short 2-Iodo-N-(6-methyl-2-pyrid­yl)benzamide
title_sort 2-iodo-n-(6-methyl-2-pyrid­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968040/
https://www.ncbi.nlm.nih.gov/pubmed/21581580
http://dx.doi.org/10.1107/S1600536808041950
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AT kiareza 2iodon6methyl2pyridylbenzamide
AT maityannadac 2iodon6methyl2pyridylbenzamide
AT maitysibaprasad 2iodon6methyl2pyridylbenzamide
AT goswamishyamaprosad 2iodon6methyl2pyridylbenzamide

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