1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide

In the title salt, C(26)H(29)N(2) (+)·Br(−), which may serve as a precursor for N-heterocyclic carbenes, the imidazolidine ring adopts a twist conformation with a pseudo-twofold axis passing through the N—C—N carbon and the opposite C—C bond. The N—C—N bond angle [113.0 (4)°] and C—N bond lengths [1...

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Autores principales: Arslan, Hakan, VanDerveer, Don, Yaşar, Sedat, Özdemir, İsmail, Çetinkaya, Bekir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968042/
https://www.ncbi.nlm.nih.gov/pubmed/21581583
http://dx.doi.org/10.1107/S1600536808042086
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author Arslan, Hakan
VanDerveer, Don
Yaşar, Sedat
Özdemir, İsmail
Çetinkaya, Bekir
author_facet Arslan, Hakan
VanDerveer, Don
Yaşar, Sedat
Özdemir, İsmail
Çetinkaya, Bekir
author_sort Arslan, Hakan
collection PubMed
description In the title salt, C(26)H(29)N(2) (+)·Br(−), which may serve as a precursor for N-heterocyclic carbenes, the imidazolidine ring adopts a twist conformation with a pseudo-twofold axis passing through the N—C—N carbon and the opposite C—C bond. The N—C—N bond angle [113.0 (4)°] and C—N bond lengths [1.313 (6) and 1.305 (6) Å] confirm the existence of strong resonance in this part of the mol­ecule. In the crystal, a C—H⋯Br inter­action is present. The dihedral angle between the biphenyl rings is 64.3 (2)° and the phenyl rings make angles of 76.6 (3) and 18.5 (3)° with the plane of the imidazolidine ring.
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spelling pubmed-29680422010-12-30 1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide Arslan, Hakan VanDerveer, Don Yaşar, Sedat Özdemir, İsmail Çetinkaya, Bekir Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(26)H(29)N(2) (+)·Br(−), which may serve as a precursor for N-heterocyclic carbenes, the imidazolidine ring adopts a twist conformation with a pseudo-twofold axis passing through the N—C—N carbon and the opposite C—C bond. The N—C—N bond angle [113.0 (4)°] and C—N bond lengths [1.313 (6) and 1.305 (6) Å] confirm the existence of strong resonance in this part of the mol­ecule. In the crystal, a C—H⋯Br inter­action is present. The dihedral angle between the biphenyl rings is 64.3 (2)° and the phenyl rings make angles of 76.6 (3) and 18.5 (3)° with the plane of the imidazolidine ring. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2968042/ /pubmed/21581583 http://dx.doi.org/10.1107/S1600536808042086 Text en © Arslan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arslan, Hakan
VanDerveer, Don
Yaşar, Sedat
Özdemir, İsmail
Çetinkaya, Bekir
1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
title 1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
title_full 1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
title_fullStr 1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
title_full_unstemmed 1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
title_short 1-(2-Phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
title_sort 1-(2-phenyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidinium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968042/
https://www.ncbi.nlm.nih.gov/pubmed/21581583
http://dx.doi.org/10.1107/S1600536808042086
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