6-Bromo-1-butylindoline-2,3-dione

There are two independent mol­ecules in the asymmetric unit of the title compound, C(12)H(12)BrNO(2). The C—C bond lengths of the two carbonyl C atoms of the five-membered rings are distinctly longer than a normal Csp (2)—Csp (2) single bond. One of the mol­ecules makes parallel self-coupled (invers...

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Detalles Bibliográficos
Autores principales: Ji, Lei, Fang, Qi, Fan, Jian-dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968054/
https://www.ncbi.nlm.nih.gov/pubmed/21581596
http://dx.doi.org/10.1107/S1600536808042098
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author Ji, Lei
Fang, Qi
Fan, Jian-dong
author_facet Ji, Lei
Fang, Qi
Fan, Jian-dong
author_sort Ji, Lei
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(12)H(12)BrNO(2). The C—C bond lengths of the two carbonyl C atoms of the five-membered rings are distinctly longer than a normal Csp (2)—Csp (2) single bond. One of the mol­ecules makes parallel self-coupled (inversion) dimers by π–π inter­actions with phen­yl–phenyl inter­planar distances of 3.403 (2) Å. The other mol­ecule also forms self-dimers at longer phen­yl–phenyl plane distances [3.649 (2) Å]. In the crystal, a C—H⋯O interaction is seen.
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spelling pubmed-29680542010-12-30 6-Bromo-1-butylindoline-2,3-dione Ji, Lei Fang, Qi Fan, Jian-dong Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(12)H(12)BrNO(2). The C—C bond lengths of the two carbonyl C atoms of the five-membered rings are distinctly longer than a normal Csp (2)—Csp (2) single bond. One of the mol­ecules makes parallel self-coupled (inversion) dimers by π–π inter­actions with phen­yl–phenyl inter­planar distances of 3.403 (2) Å. The other mol­ecule also forms self-dimers at longer phen­yl–phenyl plane distances [3.649 (2) Å]. In the crystal, a C—H⋯O interaction is seen. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2968054/ /pubmed/21581596 http://dx.doi.org/10.1107/S1600536808042098 Text en © Ji et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ji, Lei
Fang, Qi
Fan, Jian-dong
6-Bromo-1-butylindoline-2,3-dione
title 6-Bromo-1-butylindoline-2,3-dione
title_full 6-Bromo-1-butylindoline-2,3-dione
title_fullStr 6-Bromo-1-butylindoline-2,3-dione
title_full_unstemmed 6-Bromo-1-butylindoline-2,3-dione
title_short 6-Bromo-1-butylindoline-2,3-dione
title_sort 6-bromo-1-butylindoline-2,3-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968054/
https://www.ncbi.nlm.nih.gov/pubmed/21581596
http://dx.doi.org/10.1107/S1600536808042098
work_keys_str_mv AT jilei 6bromo1butylindoline23dione
AT fangqi 6bromo1butylindoline23dione
AT fanjiandong 6bromo1butylindoline23dione

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