Morpholinium 2,4,6-trinitro­phenolate

There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (−). The morpholinium cations in both mol­ecules are puckered and adopt a chair conformation. Intermolecular N—H⋯O and C—H⋯O inter­actions generate rings of motifs R (2) (1)(5) and R...

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Detalles Bibliográficos
Autores principales: Vembu, Nagarajan, Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968070/
https://www.ncbi.nlm.nih.gov/pubmed/21581614
http://dx.doi.org/10.1107/S1600536808042657
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author Vembu, Nagarajan
Fronczek, Frank R.
author_facet Vembu, Nagarajan
Fronczek, Frank R.
author_sort Vembu, Nagarajan
collection PubMed
description There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (−). The morpholinium cations in both mol­ecules are puckered and adopt a chair conformation. Intermolecular N—H⋯O and C—H⋯O inter­actions generate rings of motifs R (2) (1)(5) and R (1) (2)(6). The supra­molecular aggregation is completed by the presence of two co-operative hydrogen-bonded networks of further N—H⋯O inter­actions, which generate an infinite one-dimensional chain along the base vector [100]. Two C—H⋯π interactions are also seen.
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spelling pubmed-29680702010-12-30 Morpholinium 2,4,6-trinitro­phenolate Vembu, Nagarajan Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (−). The morpholinium cations in both mol­ecules are puckered and adopt a chair conformation. Intermolecular N—H⋯O and C—H⋯O inter­actions generate rings of motifs R (2) (1)(5) and R (1) (2)(6). The supra­molecular aggregation is completed by the presence of two co-operative hydrogen-bonded networks of further N—H⋯O inter­actions, which generate an infinite one-dimensional chain along the base vector [100]. Two C—H⋯π interactions are also seen. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968070/ /pubmed/21581614 http://dx.doi.org/10.1107/S1600536808042657 Text en © Vembu and Fronczek 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vembu, Nagarajan
Fronczek, Frank R.
Morpholinium 2,4,6-trinitro­phenolate
title Morpholinium 2,4,6-trinitro­phenolate
title_full Morpholinium 2,4,6-trinitro­phenolate
title_fullStr Morpholinium 2,4,6-trinitro­phenolate
title_full_unstemmed Morpholinium 2,4,6-trinitro­phenolate
title_short Morpholinium 2,4,6-trinitro­phenolate
title_sort morpholinium 2,4,6-trinitro­phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968070/
https://www.ncbi.nlm.nih.gov/pubmed/21581614
http://dx.doi.org/10.1107/S1600536808042657
work_keys_str_mv AT vembunagarajan morpholinium246trinitrophenolate
AT fronczekfrankr morpholinium246trinitrophenolate

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