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Piperidinium bis(2-oxidobenzoato-κ(2) O (1),O (2))borate
The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (−) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetrahedral. In the two molecules, the aromatic ri...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968082/ https://www.ncbi.nlm.nih.gov/pubmed/21581628 http://dx.doi.org/10.1107/S1600536808042608 |
| Sumario: | The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (−) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetrahedral. In the two molecules, the aromatic rings are oriented at dihedral angles of 76.27 (3) and 83.86 (3)°. The rings containing B atoms have twist-boat conformations, while the two cations adopt chair conformations. In the crystal, the component species are linked by N—H⋯O hydrogen bonds. In the crystal structure, intra- and intermolecular N—H⋯O hydrogen bonds link the molecules. |
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