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Piperidinium bis(2-oxidobenzoato-κ(2) O (1),O (2))borate
The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (−) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetrahedral. In the two molecules, the aromatic ri...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968082/ https://www.ncbi.nlm.nih.gov/pubmed/21581628 http://dx.doi.org/10.1107/S1600536808042608 |
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| author | Tang, Zhi-Hua Huang, Chaojun |
| author_facet | Tang, Zhi-Hua Huang, Chaojun |
| author_sort | Tang, Zhi-Hua |
| collection | PubMed |
| description | The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (−) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetrahedral. In the two molecules, the aromatic rings are oriented at dihedral angles of 76.27 (3) and 83.86 (3)°. The rings containing B atoms have twist-boat conformations, while the two cations adopt chair conformations. In the crystal, the component species are linked by N—H⋯O hydrogen bonds. In the crystal structure, intra- and intermolecular N—H⋯O hydrogen bonds link the molecules. |
| format | Text |
| id | pubmed-2968082 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29680822010-12-30 Piperidinium bis(2-oxidobenzoato-κ(2) O (1),O (2))borate Tang, Zhi-Hua Huang, Chaojun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (−) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetrahedral. In the two molecules, the aromatic rings are oriented at dihedral angles of 76.27 (3) and 83.86 (3)°. The rings containing B atoms have twist-boat conformations, while the two cations adopt chair conformations. In the crystal, the component species are linked by N—H⋯O hydrogen bonds. In the crystal structure, intra- and intermolecular N—H⋯O hydrogen bonds link the molecules. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968082/ /pubmed/21581628 http://dx.doi.org/10.1107/S1600536808042608 Text en © Tang and Huang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Tang, Zhi-Hua Huang, Chaojun Piperidinium bis(2-oxidobenzoato-κ(2) O (1),O (2))borate |
| title | Piperidinium bis(2-oxidobenzoato-κ(2)
O
(1),O
(2))borate |
| title_full | Piperidinium bis(2-oxidobenzoato-κ(2)
O
(1),O
(2))borate |
| title_fullStr | Piperidinium bis(2-oxidobenzoato-κ(2)
O
(1),O
(2))borate |
| title_full_unstemmed | Piperidinium bis(2-oxidobenzoato-κ(2)
O
(1),O
(2))borate |
| title_short | Piperidinium bis(2-oxidobenzoato-κ(2)
O
(1),O
(2))borate |
| title_sort | piperidinium bis(2-oxidobenzoato-κ(2)
o
(1),o
(2))borate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968082/ https://www.ncbi.nlm.nih.gov/pubmed/21581628 http://dx.doi.org/10.1107/S1600536808042608 |
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