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1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate

The title compound, C(26)H(26)N(2)S(2), was synthesized from bis­[1,3-bis­(3-phenyl­prop­yl)benzimidazolidine-2-yl­idene] and CS(2) in toluene. The mol­ecular structure is composed of a benzimidazole ring system with two phenyl­propyl substituents and a dithio­carboxyl­ate group in the 2-position. T...

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Autores principales: Akkurt, Mehmet, Yılmaz, Ülkü, Küçükbay, Hasan, Gençaslan, Mustafa, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968085/
https://www.ncbi.nlm.nih.gov/pubmed/21581631
http://dx.doi.org/10.1107/S1600536808042761
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author Akkurt, Mehmet
Yılmaz, Ülkü
Küçükbay, Hasan
Gençaslan, Mustafa
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Yılmaz, Ülkü
Küçükbay, Hasan
Gençaslan, Mustafa
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description The title compound, C(26)H(26)N(2)S(2), was synthesized from bis­[1,3-bis­(3-phenyl­prop­yl)benzimidazolidine-2-yl­idene] and CS(2) in toluene. The mol­ecular structure is composed of a benzimidazole ring system with two phenyl­propyl substituents and a dithio­carboxyl­ate group in the 2-position. The benzimidazole unit is essentially planar, with a maximum atomic deviation of 0.008 (2) Å, and makes dihedral angles of 72.72 (10) and 27.62 (12)°, with the two phenyl rings. The dihedral angle between the two phenyl rings is 55.98 (15)°. The mol­ecular packing is stabilized by a C—H⋯S inter­molecular hydrogen-bonding inter­action and a C—H⋯π inter­action between a benzene H atom and the phenyl ring of a neighbouring mol­ecule.
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spelling pubmed-29680852010-12-30 1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate Akkurt, Mehmet Yılmaz, Ülkü Küçükbay, Hasan Gençaslan, Mustafa Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(26)N(2)S(2), was synthesized from bis­[1,3-bis­(3-phenyl­prop­yl)benzimidazolidine-2-yl­idene] and CS(2) in toluene. The mol­ecular structure is composed of a benzimidazole ring system with two phenyl­propyl substituents and a dithio­carboxyl­ate group in the 2-position. The benzimidazole unit is essentially planar, with a maximum atomic deviation of 0.008 (2) Å, and makes dihedral angles of 72.72 (10) and 27.62 (12)°, with the two phenyl rings. The dihedral angle between the two phenyl rings is 55.98 (15)°. The mol­ecular packing is stabilized by a C—H⋯S inter­molecular hydrogen-bonding inter­action and a C—H⋯π inter­action between a benzene H atom and the phenyl ring of a neighbouring mol­ecule. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968085/ /pubmed/21581631 http://dx.doi.org/10.1107/S1600536808042761 Text en © Akkurt et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Yılmaz, Ülkü
Küçükbay, Hasan
Gençaslan, Mustafa
Büyükgüngör, Orhan
1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate
title 1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate
title_full 1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate
title_fullStr 1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate
title_full_unstemmed 1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate
title_short 1,3-Bis(3-phenyl­prop­yl)-1H-benzimidazol-3-ium-2-carbodithio­ate
title_sort 1,3-bis(3-phenyl­prop­yl)-1h-benzimidazol-3-ium-2-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968085/
https://www.ncbi.nlm.nih.gov/pubmed/21581631
http://dx.doi.org/10.1107/S1600536808042761
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