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3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate

In the title compound, C(28)H(31)ClO(4), the five-membered cyclo­pentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the t...

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Detalles Bibliográficos
Autores principales: Yu, Chuan-Ming, Zhou, Yong, Cheng, Jing-Li, Zhao, Jin-Hao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968092/
https://www.ncbi.nlm.nih.gov/pubmed/21581638
http://dx.doi.org/10.1107/S1600536808043043
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author Yu, Chuan-Ming
Zhou, Yong
Cheng, Jing-Li
Zhao, Jin-Hao
author_facet Yu, Chuan-Ming
Zhou, Yong
Cheng, Jing-Li
Zhao, Jin-Hao
author_sort Yu, Chuan-Ming
collection PubMed
description In the title compound, C(28)H(31)ClO(4), the five-membered cyclo­pentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the trimethyl- and chloro­phenyl rings. The dihedral angle between the two benzene rings is 15.3 (1)°. In the crystal, mol­ecules are linked through inter­molecular C—H⋯Cl hydrogen bonds, forming a chain running along the b axis.
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spelling pubmed-29680922010-12-30 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate Yu, Chuan-Ming Zhou, Yong Cheng, Jing-Li Zhao, Jin-Hao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(31)ClO(4), the five-membered cyclo­pentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the trimethyl- and chloro­phenyl rings. The dihedral angle between the two benzene rings is 15.3 (1)°. In the crystal, mol­ecules are linked through inter­molecular C—H⋯Cl hydrogen bonds, forming a chain running along the b axis. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968092/ /pubmed/21581638 http://dx.doi.org/10.1107/S1600536808043043 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yu, Chuan-Ming
Zhou, Yong
Cheng, Jing-Li
Zhao, Jin-Hao
3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
title 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
title_full 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
title_fullStr 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
title_full_unstemmed 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
title_short 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
title_sort 3-mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 2-(4-chloro­phen­yl)-3-methyl­butyrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968092/
https://www.ncbi.nlm.nih.gov/pubmed/21581638
http://dx.doi.org/10.1107/S1600536808043043
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