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3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate
In the title compound, C(28)H(31)ClO(4), the five-membered cyclopentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the t...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968092/ https://www.ncbi.nlm.nih.gov/pubmed/21581638 http://dx.doi.org/10.1107/S1600536808043043 |
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author | Yu, Chuan-Ming Zhou, Yong Cheng, Jing-Li Zhao, Jin-Hao |
author_facet | Yu, Chuan-Ming Zhou, Yong Cheng, Jing-Li Zhao, Jin-Hao |
author_sort | Yu, Chuan-Ming |
collection | PubMed |
description | In the title compound, C(28)H(31)ClO(4), the five-membered cyclopentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the trimethyl- and chlorophenyl rings. The dihedral angle between the two benzene rings is 15.3 (1)°. In the crystal, molecules are linked through intermolecular C—H⋯Cl hydrogen bonds, forming a chain running along the b axis. |
format | Text |
id | pubmed-2968092 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29680922010-12-30 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate Yu, Chuan-Ming Zhou, Yong Cheng, Jing-Li Zhao, Jin-Hao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(31)ClO(4), the five-membered cyclopentyl ring displays an envelope conformation with the atom at the flap position 0.519 (3) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 72.9 (1) and 82.4 (1)°, respectively, with the trimethyl- and chlorophenyl rings. The dihedral angle between the two benzene rings is 15.3 (1)°. In the crystal, molecules are linked through intermolecular C—H⋯Cl hydrogen bonds, forming a chain running along the b axis. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968092/ /pubmed/21581638 http://dx.doi.org/10.1107/S1600536808043043 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yu, Chuan-Ming Zhou, Yong Cheng, Jing-Li Zhao, Jin-Hao 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
title | 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
title_full | 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
title_fullStr | 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
title_full_unstemmed | 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
title_short | 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
title_sort | 3-mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-yl 2-(4-chlorophenyl)-3-methylbutyrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968092/ https://www.ncbi.nlm.nih.gov/pubmed/21581638 http://dx.doi.org/10.1107/S1600536808043043 |
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