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Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenylcyclohex-3-ene-1-t-carboxylate
In the title molecule, C(21)H(19)ClO(3), the cyclohexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 12.75 (14) and 74.16 (8)° with the phenyl and benzene rings, respectively. The dihedral angle between...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968099/ https://www.ncbi.nlm.nih.gov/pubmed/21581646 http://dx.doi.org/10.1107/S1600536808043055 |
Sumario: | In the title molecule, C(21)H(19)ClO(3), the cyclohexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 12.75 (14) and 74.16 (8)° with the phenyl and benzene rings, respectively. The dihedral angle between the latter two rings is 81.73 (12)°. Intermolecular C—H⋯O hydrogen bonds and intramolecular C—H⋯Cl contacts are found in the crystal structure; a weak C—H⋯π interaction is also present. |
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