Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate

In the title mol­ecule, C(21)H(19)ClO(3), the cyclo­hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 12.75 (14) and 74.16 (8)° with the phenyl and benzene rings, respectively. The dihedral angle between...

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Detalles Bibliográficos
Autores principales: Anuradha, N., Thiruvalluvar, A., Pandiarajan, K., Yuvaraj, C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968099/
https://www.ncbi.nlm.nih.gov/pubmed/21581646
http://dx.doi.org/10.1107/S1600536808043055
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author Anuradha, N.
Thiruvalluvar, A.
Pandiarajan, K.
Yuvaraj, C.
author_facet Anuradha, N.
Thiruvalluvar, A.
Pandiarajan, K.
Yuvaraj, C.
author_sort Anuradha, N.
collection PubMed
description In the title mol­ecule, C(21)H(19)ClO(3), the cyclo­hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 12.75 (14) and 74.16 (8)° with the phenyl and benzene rings, respectively. The dihedral angle between the latter two rings is 81.73 (12)°. Inter­molecular C—H⋯O hydrogen bonds and intra­molecular C—H⋯Cl contacts are found in the crystal structure; a weak C—H⋯π inter­action is also present.
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spelling pubmed-29680992010-12-30 Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate Anuradha, N. Thiruvalluvar, A. Pandiarajan, K. Yuvaraj, C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(21)H(19)ClO(3), the cyclo­hexene ring adopts an envelope conformation, with all substituents equatorial. The plane through its five coplanar atoms makes dihedral angles of 12.75 (14) and 74.16 (8)° with the phenyl and benzene rings, respectively. The dihedral angle between the latter two rings is 81.73 (12)°. Inter­molecular C—H⋯O hydrogen bonds and intra­molecular C—H⋯Cl contacts are found in the crystal structure; a weak C—H⋯π inter­action is also present. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968099/ /pubmed/21581646 http://dx.doi.org/10.1107/S1600536808043055 Text en © Anuradha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, N.
Thiruvalluvar, A.
Pandiarajan, K.
Yuvaraj, C.
Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
title Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
title_full Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
title_fullStr Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
title_full_unstemmed Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
title_short Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
title_sort ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl­cyclohex-3-ene-1-t-carboxylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968099/
https://www.ncbi.nlm.nih.gov/pubmed/21581646
http://dx.doi.org/10.1107/S1600536808043055
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AT pandiarajank ethyl6r2chlorophenyl2oxo4phenylcyclohex3ene1tcarboxylate
AT yuvarajc ethyl6r2chlorophenyl2oxo4phenylcyclohex3ene1tcarboxylate

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