Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate

The title compound, K(+)·C(8)H(13)BF(3)O(2) (−)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (−) ions along with a water mol­ecule. The K(+) cation is surrounded by four a...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Guadagnin, Rafael C., Stefani, Hélio A., do Canto Visentin, Lorenzo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968100/
https://www.ncbi.nlm.nih.gov/pubmed/21581647
http://dx.doi.org/10.1107/S1600536808042931
Descripción
Sumario:The title compound, K(+)·C(8)H(13)BF(3)O(2) (−)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (−) ions along with a water mol­ecule. The K(+) cation is surrounded by four anions, making close contacts with six F atoms at 2.659 (3)–2.906 (3) Å and with two O atoms at 2.806 (3) and 2.921 (3) Å in a distorted bicapped trigonal-prismatic geometry.

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