Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate

The title compound, K(+)·C(8)H(13)BF(3)O(2) (−)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (−) ions along with a water mol­ecule. The K(+) cation is surrounded by four a...

Descripción completa

Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Guadagnin, Rafael C., Stefani, Hélio A., do Canto Visentin, Lorenzo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968100/
https://www.ncbi.nlm.nih.gov/pubmed/21581647
http://dx.doi.org/10.1107/S1600536808042931
_version_ 1782189774375747584
author Zukerman-Schpector, Julio
Guadagnin, Rafael C.
Stefani, Hélio A.
do Canto Visentin, Lorenzo
author_facet Zukerman-Schpector, Julio
Guadagnin, Rafael C.
Stefani, Hélio A.
do Canto Visentin, Lorenzo
author_sort Zukerman-Schpector, Julio
collection PubMed
description The title compound, K(+)·C(8)H(13)BF(3)O(2) (−)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (−) ions along with a water mol­ecule. The K(+) cation is surrounded by four anions, making close contacts with six F atoms at 2.659 (3)–2.906 (3) Å and with two O atoms at 2.806 (3) and 2.921 (3) Å in a distorted bicapped trigonal-prismatic geometry.
format Text
id pubmed-2968100
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29681002010-12-30 Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate Zukerman-Schpector, Julio Guadagnin, Rafael C. Stefani, Hélio A. do Canto Visentin, Lorenzo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, K(+)·C(8)H(13)BF(3)O(2) (−)·H(2)O, which was obtained from the reaction of a modified form of Z-vinylic telluride via a transmetalation reaction with n-BuLi, crystallizes as K(+) and C(8)H(13)BF(3)O(2) (−) ions along with a water mol­ecule. The K(+) cation is surrounded by four anions, making close contacts with six F atoms at 2.659 (3)–2.906 (3) Å and with two O atoms at 2.806 (3) and 2.921 (3) Å in a distorted bicapped trigonal-prismatic geometry. International Union of Crystallography 2008-12-24 /pmc/articles/PMC2968100/ /pubmed/21581647 http://dx.doi.org/10.1107/S1600536808042931 Text en © Zukerman-Schpector et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zukerman-Schpector, Julio
Guadagnin, Rafael C.
Stefani, Hélio A.
do Canto Visentin, Lorenzo
Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
title Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
title_full Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
title_fullStr Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
title_full_unstemmed Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
title_short Potassium trifluoro­[(Z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
title_sort potassium trifluoro­[(z)-3-(oxan-2-yl­oxy)prop-1-en-1-yl]borate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968100/
https://www.ncbi.nlm.nih.gov/pubmed/21581647
http://dx.doi.org/10.1107/S1600536808042931
work_keys_str_mv AT zukermanschpectorjulio potassiumtrifluoroz3oxan2yloxyprop1en1ylboratemonohydrate
AT guadagninrafaelc potassiumtrifluoroz3oxan2yloxyprop1en1ylboratemonohydrate
AT stefanihelioa potassiumtrifluoroz3oxan2yloxyprop1en1ylboratemonohydrate
AT docantovisentinlorenzo potassiumtrifluoroz3oxan2yloxyprop1en1ylboratemonohydrate

Ejemplares similares