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2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate

The title compound, C(16)H(12)N(2)O(6)·2C(3)H(7)NO, lies across a crystallographic inversion centre which is situated at the midpoint of the central N—N bond. The substitution at the C=N bond adopts a trans configuration and it is essentially coplanar with the benzene ring [N—C—C—C torsion angles =...

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Autores principales: Zhang, Sheng-Sen, Cheng, Geng-Jin-Sheng, Lei, Yu, Li, Yin-Bao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968102/
https://www.ncbi.nlm.nih.gov/pubmed/21581649
http://dx.doi.org/10.1107/S1600536808043134
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author Zhang, Sheng-Sen
Cheng, Geng-Jin-Sheng
Lei, Yu
Li, Yin-Bao
author_facet Zhang, Sheng-Sen
Cheng, Geng-Jin-Sheng
Lei, Yu
Li, Yin-Bao
author_sort Zhang, Sheng-Sen
collection PubMed
description The title compound, C(16)H(12)N(2)O(6)·2C(3)H(7)NO, lies across a crystallographic inversion centre which is situated at the midpoint of the central N—N bond. The substitution at the C=N bond adopts a trans configuration and it is essentially coplanar with the benzene ring [N—C—C—C torsion angles = −173.9 (4) and 6.4 (6)°]. All torsion angles involving non-H atoms are close to 180°. Intra­molecular O—H⋯O and weak C—H⋯O hydrogen bonds form S(6) and S(5) ring motifs, respectively, while inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds connect the Schiff base mol­ecule to solvent dimethyl­formamide mol­ecules.
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spelling pubmed-29681022010-12-30 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate Zhang, Sheng-Sen Cheng, Geng-Jin-Sheng Lei, Yu Li, Yin-Bao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(12)N(2)O(6)·2C(3)H(7)NO, lies across a crystallographic inversion centre which is situated at the midpoint of the central N—N bond. The substitution at the C=N bond adopts a trans configuration and it is essentially coplanar with the benzene ring [N—C—C—C torsion angles = −173.9 (4) and 6.4 (6)°]. All torsion angles involving non-H atoms are close to 180°. Intra­molecular O—H⋯O and weak C—H⋯O hydrogen bonds form S(6) and S(5) ring motifs, respectively, while inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds connect the Schiff base mol­ecule to solvent dimethyl­formamide mol­ecules. International Union of Crystallography 2008-12-24 /pmc/articles/PMC2968102/ /pubmed/21581649 http://dx.doi.org/10.1107/S1600536808043134 Text en © Zhang and Cheng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Sheng-Sen
Cheng, Geng-Jin-Sheng
Lei, Yu
Li, Yin-Bao
2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
title 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
title_full 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
title_fullStr 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
title_full_unstemmed 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
title_short 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
title_sort 2,2′-dihydroxy-3,3′-[(1e,1′e)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid n,n-dimethylformamide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968102/
https://www.ncbi.nlm.nih.gov/pubmed/21581649
http://dx.doi.org/10.1107/S1600536808043134
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