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2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate
The title compound, C(16)H(12)N(2)O(6)·2C(3)H(7)NO, lies across a crystallographic inversion centre which is situated at the midpoint of the central N—N bond. The substitution at the C=N bond adopts a trans configuration and it is essentially coplanar with the benzene ring [N—C—C—C torsion angles =...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968102/ https://www.ncbi.nlm.nih.gov/pubmed/21581649 http://dx.doi.org/10.1107/S1600536808043134 |
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author | Zhang, Sheng-Sen Cheng, Geng-Jin-Sheng Lei, Yu Li, Yin-Bao |
author_facet | Zhang, Sheng-Sen Cheng, Geng-Jin-Sheng Lei, Yu Li, Yin-Bao |
author_sort | Zhang, Sheng-Sen |
collection | PubMed |
description | The title compound, C(16)H(12)N(2)O(6)·2C(3)H(7)NO, lies across a crystallographic inversion centre which is situated at the midpoint of the central N—N bond. The substitution at the C=N bond adopts a trans configuration and it is essentially coplanar with the benzene ring [N—C—C—C torsion angles = −173.9 (4) and 6.4 (6)°]. All torsion angles involving non-H atoms are close to 180°. Intramolecular O—H⋯O and weak C—H⋯O hydrogen bonds form S(6) and S(5) ring motifs, respectively, while intermolecular O—H⋯O and weak C—H⋯O hydrogen bonds connect the Schiff base molecule to solvent dimethylformamide molecules. |
format | Text |
id | pubmed-2968102 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681022010-12-30 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate Zhang, Sheng-Sen Cheng, Geng-Jin-Sheng Lei, Yu Li, Yin-Bao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(12)N(2)O(6)·2C(3)H(7)NO, lies across a crystallographic inversion centre which is situated at the midpoint of the central N—N bond. The substitution at the C=N bond adopts a trans configuration and it is essentially coplanar with the benzene ring [N—C—C—C torsion angles = −173.9 (4) and 6.4 (6)°]. All torsion angles involving non-H atoms are close to 180°. Intramolecular O—H⋯O and weak C—H⋯O hydrogen bonds form S(6) and S(5) ring motifs, respectively, while intermolecular O—H⋯O and weak C—H⋯O hydrogen bonds connect the Schiff base molecule to solvent dimethylformamide molecules. International Union of Crystallography 2008-12-24 /pmc/articles/PMC2968102/ /pubmed/21581649 http://dx.doi.org/10.1107/S1600536808043134 Text en © Zhang and Cheng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Sheng-Sen Cheng, Geng-Jin-Sheng Lei, Yu Li, Yin-Bao 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate |
title | 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate |
title_full | 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate |
title_fullStr | 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate |
title_full_unstemmed | 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate |
title_short | 2,2′-Dihydroxy-3,3′-[(1E,1′E)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid N,N-dimethylformamide disolvate |
title_sort | 2,2′-dihydroxy-3,3′-[(1e,1′e)-hydrazine-1,2-diylidenedimethylidyne]dibenzoic acid n,n-dimethylformamide disolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968102/ https://www.ncbi.nlm.nih.gov/pubmed/21581649 http://dx.doi.org/10.1107/S1600536808043134 |
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