(E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate

The mol­ecule of the title compound, C(18)H(16)N(2)O(4), adopts a T-shaped conformation with E stereochemistry for the imine double bond. The (3-nitro­benzyl­idene)amino fragment is almost planar, the mean planes of phenyl ring and nitro group forming a dihedral angle of 8.9 (3)°. In the 3-phenyl­ac...

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Detalles Bibliográficos
Autores principales: Bortoluzzi, Adailton J., Bisol, Tula B., Sá, Marcus M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968105/
https://www.ncbi.nlm.nih.gov/pubmed/21581652
http://dx.doi.org/10.1107/S1600536808043262
Descripción
Sumario:The mol­ecule of the title compound, C(18)H(16)N(2)O(4), adopts a T-shaped conformation with E stereochemistry for the imine double bond. The (3-nitro­benzyl­idene)amino fragment is almost planar, the mean planes of phenyl ring and nitro group forming a dihedral angle of 8.9 (3)°. In the 3-phenyl­acryloyl unit, the acrylic ester fragment is also almost planar, with the phenyl ring twisted by 41.44 (7)°. In the crystal, the mol­ecules are linked by C—H⋯O hydrogen-bond inter­actions into chains running parallel to [01[Image: see text]].

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