(E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate

The mol­ecule of the title compound, C(18)H(16)N(2)O(4), adopts a T-shaped conformation with E stereochemistry for the imine double bond. The (3-nitro­benzyl­idene)amino fragment is almost planar, the mean planes of phenyl ring and nitro group forming a dihedral angle of 8.9 (3)°. In the 3-phenyl­ac...

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Detalles Bibliográficos
Autores principales: Bortoluzzi, Adailton J., Bisol, Tula B., Sá, Marcus M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968105/
https://www.ncbi.nlm.nih.gov/pubmed/21581652
http://dx.doi.org/10.1107/S1600536808043262
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author Bortoluzzi, Adailton J.
Bisol, Tula B.
Sá, Marcus M.
author_facet Bortoluzzi, Adailton J.
Bisol, Tula B.
Sá, Marcus M.
author_sort Bortoluzzi, Adailton J.
collection PubMed
description The mol­ecule of the title compound, C(18)H(16)N(2)O(4), adopts a T-shaped conformation with E stereochemistry for the imine double bond. The (3-nitro­benzyl­idene)amino fragment is almost planar, the mean planes of phenyl ring and nitro group forming a dihedral angle of 8.9 (3)°. In the 3-phenyl­acryloyl unit, the acrylic ester fragment is also almost planar, with the phenyl ring twisted by 41.44 (7)°. In the crystal, the mol­ecules are linked by C—H⋯O hydrogen-bond inter­actions into chains running parallel to [01[Image: see text]].
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spelling pubmed-29681052010-12-30 (E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate Bortoluzzi, Adailton J. Bisol, Tula B. Sá, Marcus M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(18)H(16)N(2)O(4), adopts a T-shaped conformation with E stereochemistry for the imine double bond. The (3-nitro­benzyl­idene)amino fragment is almost planar, the mean planes of phenyl ring and nitro group forming a dihedral angle of 8.9 (3)°. In the 3-phenyl­acryloyl unit, the acrylic ester fragment is also almost planar, with the phenyl ring twisted by 41.44 (7)°. In the crystal, the mol­ecules are linked by C—H⋯O hydrogen-bond inter­actions into chains running parallel to [01[Image: see text]]. International Union of Crystallography 2008-12-24 /pmc/articles/PMC2968105/ /pubmed/21581652 http://dx.doi.org/10.1107/S1600536808043262 Text en © Bortoluzzi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bortoluzzi, Adailton J.
Bisol, Tula B.
Sá, Marcus M.
(E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
title (E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
title_full (E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
title_fullStr (E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
title_full_unstemmed (E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
title_short (E,E)-Methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
title_sort (e,e)-methyl 2-[(3-nitrobenzylidene)­aminomethyl]-3-phenylpropenoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968105/
https://www.ncbi.nlm.nih.gov/pubmed/21581652
http://dx.doi.org/10.1107/S1600536808043262
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