2-(Trimethyl­siloxy)adamantane-2-carbonitrile

In the crystal structure of the title compound, C(14)H(23)NOSi, cyclic dimeric units are established by two very weak hydrogen bonds of the type C—H⋯N with an H⋯N distance which is only slightly shorter than the sum of the van der Waals radii of 2.75 Å. The graph-set descriptor on the unitary level...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Klüfers, Peter, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968112/
https://www.ncbi.nlm.nih.gov/pubmed/21581661
http://dx.doi.org/10.1107/S1600536808043559
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author Betz, Richard
Klüfers, Peter
Mayer, Peter
author_facet Betz, Richard
Klüfers, Peter
Mayer, Peter
author_sort Betz, Richard
collection PubMed
description In the crystal structure of the title compound, C(14)H(23)NOSi, cyclic dimeric units are established by two very weak hydrogen bonds of the type C—H⋯N with an H⋯N distance which is only slightly shorter than the sum of the van der Waals radii of 2.75 Å. The graph-set descriptor on the unitary level is R (2) (2)(14) for the cyclic dimer.
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spelling pubmed-29681122010-12-30 2-(Trimethyl­siloxy)adamantane-2-carbonitrile Betz, Richard Klüfers, Peter Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(23)NOSi, cyclic dimeric units are established by two very weak hydrogen bonds of the type C—H⋯N with an H⋯N distance which is only slightly shorter than the sum of the van der Waals radii of 2.75 Å. The graph-set descriptor on the unitary level is R (2) (2)(14) for the cyclic dimer. International Union of Crystallography 2008-12-24 /pmc/articles/PMC2968112/ /pubmed/21581661 http://dx.doi.org/10.1107/S1600536808043559 Text en © Betz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Klüfers, Peter
Mayer, Peter
2-(Trimethyl­siloxy)adamantane-2-carbonitrile
title 2-(Trimethyl­siloxy)adamantane-2-carbonitrile
title_full 2-(Trimethyl­siloxy)adamantane-2-carbonitrile
title_fullStr 2-(Trimethyl­siloxy)adamantane-2-carbonitrile
title_full_unstemmed 2-(Trimethyl­siloxy)adamantane-2-carbonitrile
title_short 2-(Trimethyl­siloxy)adamantane-2-carbonitrile
title_sort 2-(trimethyl­siloxy)adamantane-2-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968112/
https://www.ncbi.nlm.nih.gov/pubmed/21581661
http://dx.doi.org/10.1107/S1600536808043559
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AT kluferspeter 2trimethylsiloxyadamantane2carbonitrile
AT mayerpeter 2trimethylsiloxyadamantane2carbonitrile

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