Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)

In the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa­hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol­ecule. The metal center is six-coordinated by two...

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Detalles Bibliográficos
Autores principales: Chang, Jiu Li, Gao, Zhi Yong, Jiang, Kai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968124/
https://www.ncbi.nlm.nih.gov/pubmed/21581785
http://dx.doi.org/10.1107/S1600536809000786
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author Chang, Jiu Li
Gao, Zhi Yong
Jiang, Kai
author_facet Chang, Jiu Li
Gao, Zhi Yong
Jiang, Kai
author_sort Chang, Jiu Li
collection PubMed
description In the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa­hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol­ecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings.
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spelling pubmed-29681242010-12-30 Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II) Chang, Jiu Li Gao, Zhi Yong Jiang, Kai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa­hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol­ecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968124/ /pubmed/21581785 http://dx.doi.org/10.1107/S1600536809000786 Text en © Chang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chang, Jiu Li
Gao, Zhi Yong
Jiang, Kai
Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)
title Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)
title_full Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)
title_fullStr Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)
title_full_unstemmed Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)
title_short Diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]manganese(II)
title_sort diazido­bis[4,4,5,5-tetra­methyl-2-(1,3-thia­zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) o,n]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968124/
https://www.ncbi.nlm.nih.gov/pubmed/21581785
http://dx.doi.org/10.1107/S1600536809000786
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AT gaozhiyong diazidobis4455tetramethyl213thiazol2yl2imidazoline1oxyl3oxidek2onmanganeseii
AT jiangkai diazidobis4455tetramethyl213thiazol2yl2imidazoline1oxyl3oxidek2onmanganeseii

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