Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate

The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra­hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl­phosphine ligands. It is an example of a new type of tropolone derivative...

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Detalles Bibliográficos
Autores principales: Steyl, Gideon, Hill, Tania N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968127/
https://www.ncbi.nlm.nih.gov/pubmed/21581823
http://dx.doi.org/10.1107/S1600536809002785
Descripción
Sumario:The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra­hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl­phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.

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