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Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate

The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra­hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl­phosphine ligands. It is an example of a new type of tropolone derivative...

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Detalles Bibliográficos
Autores principales: Steyl, Gideon, Hill, Tania N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968127/
https://www.ncbi.nlm.nih.gov/pubmed/21581823
http://dx.doi.org/10.1107/S1600536809002785
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author Steyl, Gideon
Hill, Tania N.
author_facet Steyl, Gideon
Hill, Tania N.
author_sort Steyl, Gideon
collection PubMed
description The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra­hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl­phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.
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spelling pubmed-29681272010-12-30 Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate Steyl, Gideon Hill, Tania N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra­hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl­phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968127/ /pubmed/21581823 http://dx.doi.org/10.1107/S1600536809002785 Text en © Steyl and Hill 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Steyl, Gideon
Hill, Tania N.
Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate
title Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate
title_full Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate
title_fullStr Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate
title_full_unstemmed Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate
title_short Bis(triphenyl­phosphine-κP)(tropolonato-κ(2) O,O′)silver(I) dichloro­methane solvate
title_sort bis(triphenyl­phosphine-κp)(tropolonato-κ(2) o,o′)silver(i) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968127/
https://www.ncbi.nlm.nih.gov/pubmed/21581823
http://dx.doi.org/10.1107/S1600536809002785
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