Cargando…
(2,2′-Bipyridine-κ(2) N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) O (2),N (1),S)zinc(II)
The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N′-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O—H⋯O and N—H⋯N hydrogen bonds link adjacent molecules into a layer struct...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968129/ https://www.ncbi.nlm.nih.gov/pubmed/21581758 http://dx.doi.org/10.1107/S1600536808043973 |
_version_ | 1782189782958342144 |
---|---|
author | Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng |
author_facet | Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng |
author_sort | Tan, Kong Wai |
collection | PubMed |
description | The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N′-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O—H⋯O and N—H⋯N hydrogen bonds link adjacent molecules into a layer structure. |
format | Text |
id | pubmed-2968129 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681292010-12-30 (2,2′-Bipyridine-κ(2) N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) O (2),N (1),S)zinc(II) Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N′-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O—H⋯O and N—H⋯N hydrogen bonds link adjacent molecules into a layer structure. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968129/ /pubmed/21581758 http://dx.doi.org/10.1107/S1600536808043973 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng (2,2′-Bipyridine-κ(2) N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) O (2),N (1),S)zinc(II) |
title | (2,2′-Bipyridine-κ(2)
N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)zinc(II) |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)zinc(II) |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)zinc(II) |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)zinc(II) |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)zinc(II) |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
o
(2),n
(1),s)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968129/ https://www.ncbi.nlm.nih.gov/pubmed/21581758 http://dx.doi.org/10.1107/S1600536808043973 |
work_keys_str_mv | AT tankongwai 22bipyridinek2nn4hydroxy2oxidobenzaldehydethiosemicarbazonatok3o2n1szincii AT ngchewhee 22bipyridinek2nn4hydroxy2oxidobenzaldehydethiosemicarbazonatok3o2n1szincii AT maahmohdjamil 22bipyridinek2nn4hydroxy2oxidobenzaldehydethiosemicarbazonatok3o2n1szincii AT ngseikweng 22bipyridinek2nn4hydroxy2oxidobenzaldehydethiosemicarbazonatok3o2n1szincii |