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(2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)

The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N′-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O—H⋯O and N—H⋯N hydrogen bonds link adjacent mol­ecules into a layer struct...

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Detalles Bibliográficos
Autores principales: Tan, Kong Wai, Ng, Chew Hee, Maah, Mohd Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968129/
https://www.ncbi.nlm.nih.gov/pubmed/21581758
http://dx.doi.org/10.1107/S1600536808043973
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author Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
author_facet Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
author_sort Tan, Kong Wai
collection PubMed
description The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N′-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O—H⋯O and N—H⋯N hydrogen bonds link adjacent mol­ecules into a layer structure.
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spelling pubmed-29681292010-12-30 (2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II) Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(10)H(8)N(2))], is N,N′-chelated by the heterocycle and N,O,S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O—H⋯O and N—H⋯N hydrogen bonds link adjacent mol­ecules into a layer structure. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968129/ /pubmed/21581758 http://dx.doi.org/10.1107/S1600536808043973 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
(2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)
title (2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)
title_full (2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)
title_short (2,2′-Bipyridine-κ(2) N,N′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) O (2),N (1),S)zinc(II)
title_sort (2,2′-bipyridine-κ(2) n,n′)(4-hydr­oxy-2-oxidobenzaldehyde thio­semicar­ba­zon­ato-κ(3) o (2),n (1),s)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968129/
https://www.ncbi.nlm.nih.gov/pubmed/21581758
http://dx.doi.org/10.1107/S1600536808043973
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