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{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate

In the title complex, [NiSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(4)O)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a deprotonated Schiff base ligand and by two O atoms of two methanol ligands in a slightly distorted octa­hedral geometry. The Sm(III) ion is coordinated by...

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Detalles Bibliográficos
Autor principal: Liu, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968130/
https://www.ncbi.nlm.nih.gov/pubmed/21581745
http://dx.doi.org/10.1107/S1600536808038920
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author Liu, Fei
author_facet Liu, Fei
author_sort Liu, Fei
collection PubMed
description In the title complex, [NiSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(4)O)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a deprotonated Schiff base ligand and by two O atoms of two methanol ligands in a slightly distorted octa­hedral geometry. The Sm(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand in a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules, forming (10[Image: see text]) sheets.
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spelling pubmed-29681302010-12-30 {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate Liu, Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [NiSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(4)O)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a deprotonated Schiff base ligand and by two O atoms of two methanol ligands in a slightly distorted octa­hedral geometry. The Sm(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand in a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules, forming (10[Image: see text]) sheets. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968130/ /pubmed/21581745 http://dx.doi.org/10.1107/S1600536808038920 Text en © Fei Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Fei
{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate
title {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate
title_full {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate
title_short {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)samarium(III) methanol disolvate
title_sort {μ-6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(ii)samarium(iii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968130/
https://www.ncbi.nlm.nih.gov/pubmed/21581745
http://dx.doi.org/10.1107/S1600536808038920
work_keys_str_mv AT liufei m66dimethoxy22propane13diylbisnitrilomethylidynediphenolatodimethanoltrinitratonickeliisamariumiiimethanoldisolvate