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Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate

In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N′-(2-hydroxy­benzil­idene)aceto­hydrazide and copper(II) chloride, the Cu(II) atom is coord­inated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The tw...

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Autores principales: Tamboura, Farba Bouyagui, Gaye, Mohamed, Sall, Abdou Salam, Barry, Aliou Hamady, Bah, Youssouph
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968131/
https://www.ncbi.nlm.nih.gov/pubmed/21581771
http://dx.doi.org/10.1107/S1600536809000105
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author Tamboura, Farba Bouyagui
Gaye, Mohamed
Sall, Abdou Salam
Barry, Aliou Hamady
Bah, Youssouph
author_facet Tamboura, Farba Bouyagui
Gaye, Mohamed
Sall, Abdou Salam
Barry, Aliou Hamady
Bah, Youssouph
author_sort Tamboura, Farba Bouyagui
collection PubMed
description In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N′-(2-hydroxy­benzil­idene)aceto­hydrazide and copper(II) chloride, the Cu(II) atom is coord­inated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The two donor O atoms of the tridentate Schiff base ligand are in a trans arrangement. In the crystal structure, there is an extensive inter­molecular hydrogen-bonding network; N—H⋯O, O—H⋯O and O—H⋯Cl inter­actions, involving the uncoordinated water mol­ecules, lead to the formation of a two-dimensional network parallel to the ab plane.
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spelling pubmed-29681312010-12-30 Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate Tamboura, Farba Bouyagui Gaye, Mohamed Sall, Abdou Salam Barry, Aliou Hamady Bah, Youssouph Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N′-(2-hydroxy­benzil­idene)aceto­hydrazide and copper(II) chloride, the Cu(II) atom is coord­inated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The two donor O atoms of the tridentate Schiff base ligand are in a trans arrangement. In the crystal structure, there is an extensive inter­molecular hydrogen-bonding network; N—H⋯O, O—H⋯O and O—H⋯Cl inter­actions, involving the uncoordinated water mol­ecules, lead to the formation of a two-dimensional network parallel to the ab plane. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968131/ /pubmed/21581771 http://dx.doi.org/10.1107/S1600536809000105 Text en © Tamboura et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tamboura, Farba Bouyagui
Gaye, Mohamed
Sall, Abdou Salam
Barry, Aliou Hamady
Bah, Youssouph
Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
title Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
title_full Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
title_fullStr Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
title_full_unstemmed Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
title_short Chlorido[N′-(2-oxidobenzil­idene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
title_sort chlorido[n′-(2-oxidobenzil­idene)acetohydrazide-κ(2) o,n′,o′]copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968131/
https://www.ncbi.nlm.nih.gov/pubmed/21581771
http://dx.doi.org/10.1107/S1600536809000105
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