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Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate
In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N′-(2-hydroxybenzilidene)acetohydrazide and copper(II) chloride, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The tw...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968131/ https://www.ncbi.nlm.nih.gov/pubmed/21581771 http://dx.doi.org/10.1107/S1600536809000105 |
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author | Tamboura, Farba Bouyagui Gaye, Mohamed Sall, Abdou Salam Barry, Aliou Hamady Bah, Youssouph |
author_facet | Tamboura, Farba Bouyagui Gaye, Mohamed Sall, Abdou Salam Barry, Aliou Hamady Bah, Youssouph |
author_sort | Tamboura, Farba Bouyagui |
collection | PubMed |
description | In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N′-(2-hydroxybenzilidene)acetohydrazide and copper(II) chloride, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The two donor O atoms of the tridentate Schiff base ligand are in a trans arrangement. In the crystal structure, there is an extensive intermolecular hydrogen-bonding network; N—H⋯O, O—H⋯O and O—H⋯Cl interactions, involving the uncoordinated water molecules, lead to the formation of a two-dimensional network parallel to the ab plane. |
format | Text |
id | pubmed-2968131 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681312010-12-30 Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate Tamboura, Farba Bouyagui Gaye, Mohamed Sall, Abdou Salam Barry, Aliou Hamady Bah, Youssouph Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(9)H(9)N(2)O(2))Cl]·2H(2)O, prepared from the Schiff base ligand N′-(2-hydroxybenzilidene)acetohydrazide and copper(II) chloride, the Cu(II) atom is coordinated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The two donor O atoms of the tridentate Schiff base ligand are in a trans arrangement. In the crystal structure, there is an extensive intermolecular hydrogen-bonding network; N—H⋯O, O—H⋯O and O—H⋯Cl interactions, involving the uncoordinated water molecules, lead to the formation of a two-dimensional network parallel to the ab plane. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968131/ /pubmed/21581771 http://dx.doi.org/10.1107/S1600536809000105 Text en © Tamboura et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tamboura, Farba Bouyagui Gaye, Mohamed Sall, Abdou Salam Barry, Aliou Hamady Bah, Youssouph Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2) O,N′,O′]copper(II) dihydrate |
title | Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2)
O,N′,O′]copper(II) dihydrate |
title_full | Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2)
O,N′,O′]copper(II) dihydrate |
title_fullStr | Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2)
O,N′,O′]copper(II) dihydrate |
title_full_unstemmed | Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2)
O,N′,O′]copper(II) dihydrate |
title_short | Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ(2)
O,N′,O′]copper(II) dihydrate |
title_sort | chlorido[n′-(2-oxidobenzilidene)acetohydrazide-κ(2)
o,n′,o′]copper(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968131/ https://www.ncbi.nlm.nih.gov/pubmed/21581771 http://dx.doi.org/10.1107/S1600536809000105 |
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