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Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) molecule, one water molecule and two monodentate 2-hydroxybenzoate anions in a distorted trigonal-bip...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968132/ https://www.ncbi.nlm.nih.gov/pubmed/21581794 http://dx.doi.org/10.1107/S1600536809000981 |
Sumario: | In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) molecule, one water molecule and two monodentate 2-hydroxybenzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxybenzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-molecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, molecules are linked into a two-dimensional framework by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The packing of the structure is further stabilized by π–π stacking interactions involving dmphen molecules, with centroid–centroid separations of 3.8027 (3) and 3.6319 (3) Å. |
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