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Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate

In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol­ecule, one water mol­ecule and two monodentate 2-hydroxy­benzoate anions in a distorted trigonal-bip...

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Detalles Bibliográficos
Autores principales: Zhao, Pei-Zheng, Yan, Feng-Mei, Wang, Jian-Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968132/
https://www.ncbi.nlm.nih.gov/pubmed/21581794
http://dx.doi.org/10.1107/S1600536809000981
Descripción
Sumario:In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol­ecule, one water mol­ecule and two monodentate 2-hydroxy­benzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxy­benzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-mol­ecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, mol­ecules are linked into a two-dimensional framework by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The packing of the structure is further stabilized by π–π stacking inter­actions involving dmphen mol­ecules, with centroid–centroid separations of 3.8027 (3) and 3.6319 (3) Å.