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Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) molecule, one water molecule and two monodentate 2-hydroxybenzoate anions in a distorted trigonal-bip...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968132/ https://www.ncbi.nlm.nih.gov/pubmed/21581794 http://dx.doi.org/10.1107/S1600536809000981 |
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author | Zhao, Pei-Zheng Yan, Feng-Mei Wang, Jian-Ge |
author_facet | Zhao, Pei-Zheng Yan, Feng-Mei Wang, Jian-Ge |
author_sort | Zhao, Pei-Zheng |
collection | PubMed |
description | In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) molecule, one water molecule and two monodentate 2-hydroxybenzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxybenzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-molecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, molecules are linked into a two-dimensional framework by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The packing of the structure is further stabilized by π–π stacking interactions involving dmphen molecules, with centroid–centroid separations of 3.8027 (3) and 3.6319 (3) Å. |
format | Text |
id | pubmed-2968132 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681322010-12-30 Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate Zhao, Pei-Zheng Yan, Feng-Mei Wang, Jian-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) molecule, one water molecule and two monodentate 2-hydroxybenzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxybenzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-molecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, molecules are linked into a two-dimensional framework by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The packing of the structure is further stabilized by π–π stacking interactions involving dmphen molecules, with centroid–centroid separations of 3.8027 (3) and 3.6319 (3) Å. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968132/ /pubmed/21581794 http://dx.doi.org/10.1107/S1600536809000981 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Pei-Zheng Yan, Feng-Mei Wang, Jian-Ge Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
title | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
title_full | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
title_fullStr | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
title_full_unstemmed | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
title_short | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
title_sort | aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)bis(2-hydroxybenzoato-κo)manganese(ii) 2,9-dimethyl-1,10-phenanthroline hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968132/ https://www.ncbi.nlm.nih.gov/pubmed/21581794 http://dx.doi.org/10.1107/S1600536809000981 |
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