Cargando…

Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate

In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol­ecule, one water mol­ecule and two monodentate 2-hydroxy­benzoate anions in a distorted trigonal-bip...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Pei-Zheng, Yan, Feng-Mei, Wang, Jian-Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968132/
https://www.ncbi.nlm.nih.gov/pubmed/21581794
http://dx.doi.org/10.1107/S1600536809000981
_version_ 1782189783783571456
author Zhao, Pei-Zheng
Yan, Feng-Mei
Wang, Jian-Ge
author_facet Zhao, Pei-Zheng
Yan, Feng-Mei
Wang, Jian-Ge
author_sort Zhao, Pei-Zheng
collection PubMed
description In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol­ecule, one water mol­ecule and two monodentate 2-hydroxy­benzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxy­benzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-mol­ecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, mol­ecules are linked into a two-dimensional framework by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The packing of the structure is further stabilized by π–π stacking inter­actions involving dmphen mol­ecules, with centroid–centroid separations of 3.8027 (3) and 3.6319 (3) Å.
format Text
id pubmed-2968132
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29681322010-12-30 Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate Zhao, Pei-Zheng Yan, Feng-Mei Wang, Jian-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol­ecule, one water mol­ecule and two monodentate 2-hydroxy­benzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxy­benzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-mol­ecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, mol­ecules are linked into a two-dimensional framework by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The packing of the structure is further stabilized by π–π stacking inter­actions involving dmphen mol­ecules, with centroid–centroid separations of 3.8027 (3) and 3.6319 (3) Å. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968132/ /pubmed/21581794 http://dx.doi.org/10.1107/S1600536809000981 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Pei-Zheng
Yan, Feng-Mei
Wang, Jian-Ge
Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
title Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
title_full Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
title_fullStr Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
title_full_unstemmed Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
title_short Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-hydroxy­benzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
title_sort aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)bis­(2-hydroxy­benzoato-κo)manganese(ii) 2,9-dimethyl-1,10-phenanthroline hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968132/
https://www.ncbi.nlm.nih.gov/pubmed/21581794
http://dx.doi.org/10.1107/S1600536809000981
work_keys_str_mv AT zhaopeizheng aqua29dimethyl110phenanthrolinek2nnbis2hydroxybenzoatokomanganeseii29dimethyl110phenanthrolinehemisolvate
AT yanfengmei aqua29dimethyl110phenanthrolinek2nnbis2hydroxybenzoatokomanganeseii29dimethyl110phenanthrolinehemisolvate
AT wangjiange aqua29dimethyl110phenanthrolinek2nnbis2hydroxybenzoatokomanganeseii29dimethyl110phenanthrolinehemisolvate