LiHo(PO(3))(4)

Lithium holmium(III) polyphosphate(V), LiHo(PO(3))(4), belongs to the type I of polyphosphates with general formula ALn(PO(3))(4), where A is a monovalent cation and Ln is a trivalent rare earth cation. In the crystal structure, the polyphosphate chains spread along the b-axis direction, with a repe...

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Detalles Bibliográficos
Autores principales: Ben Zarkouna, Emna, Driss, Ahmed, Férid, Mokhtar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968134/
https://www.ncbi.nlm.nih.gov/pubmed/21581738
http://dx.doi.org/10.1107/S1600536809001767
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author Ben Zarkouna, Emna
Driss, Ahmed
Férid, Mokhtar
author_facet Ben Zarkouna, Emna
Driss, Ahmed
Férid, Mokhtar
author_sort Ben Zarkouna, Emna
collection PubMed
description Lithium holmium(III) polyphosphate(V), LiHo(PO(3))(4), belongs to the type I of polyphosphates with general formula ALn(PO(3))(4), where A is a monovalent cation and Ln is a trivalent rare earth cation. In the crystal structure, the polyphosphate chains spread along the b-axis direction, with a repeat period of four tetra­hedra and 2(1) inter­nal symmetry. The Li and Ho atoms are both located on twofold rotation axes and are surrounded by four and eight O atoms, leading to a distorted tetra­hedral and dodeca­hedral coordination, respectively. The HoO(8) polyhedra are isolated from each other, the closest Ho⋯Ho distance being 5.570 (1) Å.
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spelling pubmed-29681342010-12-30 LiHo(PO(3))(4) Ben Zarkouna, Emna Driss, Ahmed Férid, Mokhtar Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Lithium holmium(III) polyphosphate(V), LiHo(PO(3))(4), belongs to the type I of polyphosphates with general formula ALn(PO(3))(4), where A is a monovalent cation and Ln is a trivalent rare earth cation. In the crystal structure, the polyphosphate chains spread along the b-axis direction, with a repeat period of four tetra­hedra and 2(1) inter­nal symmetry. The Li and Ho atoms are both located on twofold rotation axes and are surrounded by four and eight O atoms, leading to a distorted tetra­hedral and dodeca­hedral coordination, respectively. The HoO(8) polyhedra are isolated from each other, the closest Ho⋯Ho distance being 5.570 (1) Å. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968134/ /pubmed/21581738 http://dx.doi.org/10.1107/S1600536809001767 Text en © Ben Zarkouna et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ben Zarkouna, Emna
Driss, Ahmed
Férid, Mokhtar
LiHo(PO(3))(4)
title LiHo(PO(3))(4)
title_full LiHo(PO(3))(4)
title_fullStr LiHo(PO(3))(4)
title_full_unstemmed LiHo(PO(3))(4)
title_short LiHo(PO(3))(4)
title_sort liho(po(3))(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968134/
https://www.ncbi.nlm.nih.gov/pubmed/21581738
http://dx.doi.org/10.1107/S1600536809001767
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AT drissahmed lihopo34
AT feridmokhtar lihopo34

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