(18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)

The asymmetric unit of the title compound, [K(C(3)H(3)N(2))(C(12)H(24)O(6))], is composed of a potassium cation bonded to the six O atoms of a crown ether mol­ecule and the two N atoms of a pyrazolate anion. The K⋯O distances range from 2.8416 (8) to 3.0025 (8) Å, and the two K⋯N distances are 2.744...

Descripción completa

Detalles Bibliográficos
Autores principales: Kunz, Kerstin, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968139/
https://www.ncbi.nlm.nih.gov/pubmed/21581778
http://dx.doi.org/10.1107/S1600536808043237
Descripción
Sumario:The asymmetric unit of the title compound, [K(C(3)H(3)N(2))(C(12)H(24)O(6))], is composed of a potassium cation bonded to the six O atoms of a crown ether mol­ecule and the two N atoms of a pyrazolate anion. The K⋯O distances range from 2.8416 (8) to 3.0025 (8) Å, and the two K⋯N distances are 2.7441 (11) and 2.7654 (11) Å. The K cation is displaced by 0.8437 (4) Å from the best plane through the six O atoms. The latter plane is almost perpendicular to the plane of the pyrazolate ring [dihedral angle 83.93 (3)°].

Ejemplares similares