(18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)

The asymmetric unit of the title compound, [K(C(3)H(3)N(2))(C(12)H(24)O(6))], is composed of a potassium cation bonded to the six O atoms of a crown ether mol­ecule and the two N atoms of a pyrazolate anion. The K⋯O distances range from 2.8416 (8) to 3.0025 (8) Å, and the two K⋯N distances are 2.744...

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Detalles Bibliográficos
Autores principales: Kunz, Kerstin, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968139/
https://www.ncbi.nlm.nih.gov/pubmed/21581778
http://dx.doi.org/10.1107/S1600536808043237
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author Kunz, Kerstin
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Kunz, Kerstin
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Kunz, Kerstin
collection PubMed
description The asymmetric unit of the title compound, [K(C(3)H(3)N(2))(C(12)H(24)O(6))], is composed of a potassium cation bonded to the six O atoms of a crown ether mol­ecule and the two N atoms of a pyrazolate anion. The K⋯O distances range from 2.8416 (8) to 3.0025 (8) Å, and the two K⋯N distances are 2.7441 (11) and 2.7654 (11) Å. The K cation is displaced by 0.8437 (4) Å from the best plane through the six O atoms. The latter plane is almost perpendicular to the plane of the pyrazolate ring [dihedral angle 83.93 (3)°].
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spelling pubmed-29681392010-12-30 (18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I) Kunz, Kerstin Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [K(C(3)H(3)N(2))(C(12)H(24)O(6))], is composed of a potassium cation bonded to the six O atoms of a crown ether mol­ecule and the two N atoms of a pyrazolate anion. The K⋯O distances range from 2.8416 (8) to 3.0025 (8) Å, and the two K⋯N distances are 2.7441 (11) and 2.7654 (11) Å. The K cation is displaced by 0.8437 (4) Å from the best plane through the six O atoms. The latter plane is almost perpendicular to the plane of the pyrazolate ring [dihedral angle 83.93 (3)°]. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968139/ /pubmed/21581778 http://dx.doi.org/10.1107/S1600536808043237 Text en © Kunz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kunz, Kerstin
Lerner, Hans-Wolfram
Bolte, Michael
(18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)
title (18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)
title_full (18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)
title_fullStr (18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)
title_full_unstemmed (18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)
title_short (18-Crown-6-κ(6) O)(pyrazolato-κ(2) N,N′)-potassium(I)
title_sort (18-crown-6-κ(6) o)(pyrazolato-κ(2) n,n′)-potassium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968139/
https://www.ncbi.nlm.nih.gov/pubmed/21581778
http://dx.doi.org/10.1107/S1600536808043237
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