Cargando…
Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II)
The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitriledithiolate or 1,2-dicyano-1,2-ethylenedithiolate) and an (E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium cation...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968142/ https://www.ncbi.nlm.nih.gov/pubmed/21581801 http://dx.doi.org/10.1107/S1600536809001159 |
_version_ | 1782189786516160512 |
---|---|
author | Liu, Jian-Lan Yao, Bing-Qian Liu, Qi Zhang, Shao-Ming |
author_facet | Liu, Jian-Lan Yao, Bing-Qian Liu, Qi Zhang, Shao-Ming |
author_sort | Liu, Jian-Lan |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitriledithiolate or 1,2-dicyano-1,2-ethylenedithiolate) and an (E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium cation. In the anion, the coordination around the Ni atom is a distorted square. In the cation, the aromatic rings are oriented at a dihedral angle of 7.81 (3)°. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link the cations and anions. π–π Contacts between the nickel dithiolene and pyridine rings and between the benzene and pyridine rings, [centroid–centroid distances = 3.682 (3) and 3.643 (3) Å, respectively] may further stabilize the structure. |
format | Text |
id | pubmed-2968142 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681422010-12-30 Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) Liu, Jian-Lan Yao, Bing-Qian Liu, Qi Zhang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitriledithiolate or 1,2-dicyano-1,2-ethylenedithiolate) and an (E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium cation. In the anion, the coordination around the Ni atom is a distorted square. In the cation, the aromatic rings are oriented at a dihedral angle of 7.81 (3)°. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link the cations and anions. π–π Contacts between the nickel dithiolene and pyridine rings and between the benzene and pyridine rings, [centroid–centroid distances = 3.682 (3) and 3.643 (3) Å, respectively] may further stabilize the structure. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968142/ /pubmed/21581801 http://dx.doi.org/10.1107/S1600536809001159 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jian-Lan Yao, Bing-Qian Liu, Qi Zhang, Shao-Ming Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) |
title | Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) |
title_full | Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) |
title_fullStr | Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) |
title_full_unstemmed | Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) |
title_short | Bis[(E)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(II) |
title_sort | bis[(e)-1-(3,4-dichlorobenzylideneamino)-4-methylpyridinium] bis(maleonitriledithiolato)nickelate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968142/ https://www.ncbi.nlm.nih.gov/pubmed/21581801 http://dx.doi.org/10.1107/S1600536809001159 |
work_keys_str_mv | AT liujianlan bise134dichlorobenzylideneamino4methylpyridiniumbismaleonitriledithiolatonickelateii AT yaobingqian bise134dichlorobenzylideneamino4methylpyridiniumbismaleonitriledithiolatonickelateii AT liuqi bise134dichlorobenzylideneamino4methylpyridiniumbismaleonitriledithiolatonickelateii AT zhangshaoming bise134dichlorobenzylideneamino4methylpyridiniumbismaleonitriledithiolatonickelateii |