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Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)

The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitrile­dithiol­ate or 1,2-dicyano-1,2-ethyl­enedithiol­ate) and an (E)-1-(3,4-dichloro­benzyl­ideneamino)-4-methyl­pyridinium cation...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Lan, Yao, Bing-Qian, Liu, Qi, Zhang, Shao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968142/
https://www.ncbi.nlm.nih.gov/pubmed/21581801
http://dx.doi.org/10.1107/S1600536809001159
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author Liu, Jian-Lan
Yao, Bing-Qian
Liu, Qi
Zhang, Shao-Ming
author_facet Liu, Jian-Lan
Yao, Bing-Qian
Liu, Qi
Zhang, Shao-Ming
author_sort Liu, Jian-Lan
collection PubMed
description The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitrile­dithiol­ate or 1,2-dicyano-1,2-ethyl­enedithiol­ate) and an (E)-1-(3,4-dichloro­benzyl­ideneamino)-4-methyl­pyridinium cation. In the anion, the coordination around the Ni atom is a distorted square. In the cation, the aromatic rings are oriented at a dihedral angle of 7.81 (3)°. In the crystal structure, inter­molecular C—H⋯N hydrogen bonds link the cations and anions. π–π Contacts between the nickel dithiol­ene and pyridine rings and between the benzene and pyridine rings, [centroid–centroid distances = 3.682 (3) and 3.643 (3) Å, respectively] may further stabilize the structure.
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spelling pubmed-29681422010-12-30 Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II) Liu, Jian-Lan Yao, Bing-Qian Liu, Qi Zhang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one-half of a centrosymmetric [Ni(mnt)(2)] anion (where mnt is maleonitrile­dithiol­ate or 1,2-dicyano-1,2-ethyl­enedithiol­ate) and an (E)-1-(3,4-dichloro­benzyl­ideneamino)-4-methyl­pyridinium cation. In the anion, the coordination around the Ni atom is a distorted square. In the cation, the aromatic rings are oriented at a dihedral angle of 7.81 (3)°. In the crystal structure, inter­molecular C—H⋯N hydrogen bonds link the cations and anions. π–π Contacts between the nickel dithiol­ene and pyridine rings and between the benzene and pyridine rings, [centroid–centroid distances = 3.682 (3) and 3.643 (3) Å, respectively] may further stabilize the structure. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968142/ /pubmed/21581801 http://dx.doi.org/10.1107/S1600536809001159 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jian-Lan
Yao, Bing-Qian
Liu, Qi
Zhang, Shao-Ming
Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_full Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_fullStr Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_full_unstemmed Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_short Bis[(E)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(II)
title_sort bis[(e)-1-(3,4-dichloro­benzyl­idene­amino)-4-methyl­pyridinium] bis­(maleonitrile­dithiol­ato)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968142/
https://www.ncbi.nlm.nih.gov/pubmed/21581801
http://dx.doi.org/10.1107/S1600536809001159
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