trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)

In the title compound, [Zn(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Zn(II) atom lies on an inversion centre, and is coordinated in a distorted octa­hedral geometry by two carbonyl O atoms and two imino N atoms from two anionic bidentate acetone (2-hydroxy­benzo­yl)hydrazone ligands and by two N at...

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Detalles Bibliográficos
Autores principales: Yang, Ming-Xing, Lin, Shen, Chen, Li-Juan, Chen, Xiao-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968143/
https://www.ncbi.nlm.nih.gov/pubmed/21581812
http://dx.doi.org/10.1107/S1600536809001949
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author Yang, Ming-Xing
Lin, Shen
Chen, Li-Juan
Chen, Xiao-Hua
author_facet Yang, Ming-Xing
Lin, Shen
Chen, Li-Juan
Chen, Xiao-Hua
author_sort Yang, Ming-Xing
collection PubMed
description In the title compound, [Zn(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Zn(II) atom lies on an inversion centre, and is coordinated in a distorted octa­hedral geometry by two carbonyl O atoms and two imino N atoms from two anionic bidentate acetone (2-hydroxy­benzo­yl)hydrazone ligands and by two N atoms from two pyridine mol­ecules. The hydroxyl group acts as a donor, forming an intra­molecular O—H⋯N hydrogen bond.
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spelling pubmed-29681432010-12-30 trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II) Yang, Ming-Xing Lin, Shen Chen, Li-Juan Chen, Xiao-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Zn(II) atom lies on an inversion centre, and is coordinated in a distorted octa­hedral geometry by two carbonyl O atoms and two imino N atoms from two anionic bidentate acetone (2-hydroxy­benzo­yl)hydrazone ligands and by two N atoms from two pyridine mol­ecules. The hydroxyl group acts as a donor, forming an intra­molecular O—H⋯N hydrogen bond. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968143/ /pubmed/21581812 http://dx.doi.org/10.1107/S1600536809001949 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Ming-Xing
Lin, Shen
Chen, Li-Juan
Chen, Xiao-Hua
trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)
title trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)
title_full trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)
title_fullStr trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)
title_full_unstemmed trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)
title_short trans-Bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) N′,O]bis­(pyridine-κN)zinc(II)
title_sort trans-bis[acetone (2-hydroxy­benzo­yl)hydrazonato-κ(2) n′,o]bis­(pyridine-κn)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968143/
https://www.ncbi.nlm.nih.gov/pubmed/21581812
http://dx.doi.org/10.1107/S1600536809001949
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AT chenxiaohua transbisacetone2hydroxybenzoylhydrazonatok2nobispyridineknzincii

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