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Ethyl 5-amino-1-(4-chloro-2-nitrophenyl)-1H-pyrazole-4-carboxylate
In the molecule of the title compound, C(12)H(11)ClN(4)O(4), the pyrazole ring is coplanar with the amino and ethoxycarbonyl groups within 0.026 (2) and 0.105 (2) Å, respectively. The C (6) ring of the 4-chloro-2-nitrophenyl group is twisted by 53.58 (4)° relative to the plane of the pyrazole rin...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968147/ https://www.ncbi.nlm.nih.gov/pubmed/21581889 http://dx.doi.org/10.1107/S1600536809000488 |
Sumario: | In the molecule of the title compound, C(12)H(11)ClN(4)O(4), the pyrazole ring is coplanar with the amino and ethoxycarbonyl groups within 0.026 (2) and 0.105 (2) Å, respectively. The C (6) ring of the 4-chloro-2-nitrophenyl group is twisted by 53.58 (4)° relative to the plane of the pyrazole ring. The planar structure of the pyrazole ring is stabilized by an intramolecular N—H⋯O hydrogen bond between its substituents. Neighbouring molecules are linked through intermolecular N—H⋯N and N—H⋯O hydrogen bonds, giving rise to one-dimensional tapes along the b axis. Molecules in the chain are linked to those of an adjacent chain through weak C—H⋯O interactions, forming a three-dimensional network. |
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