Poly[(3-nitro­benzoato)(μ(3)-1,2,4-triazolato)cobalt(II)]

In the title compound, [Co(C(2)H(2)N(3))(C(7)H(4)NO(4))](n), the Co(II) atom is five-coordinated by three triazolate ligands and one bidentate 3-nitro­benzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the Co(II) atoms, generating a two-dimensional net paralle...

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Detalles Bibliográficos
Autor principal: Qi, Xu-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968154/
https://www.ncbi.nlm.nih.gov/pubmed/21581750
http://dx.doi.org/10.1107/S1600536808043596
Descripción
Sumario:In the title compound, [Co(C(2)H(2)N(3))(C(7)H(4)NO(4))](n), the Co(II) atom is five-coordinated by three triazolate ligands and one bidentate 3-nitro­benzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the Co(II) atoms, generating a two-dimensional net parallel to the ab plane, in which both the Co(II) atom and the triazolate ligand act as three-connected nodes. Two weak inter­molecular C—H⋯O hydrogen bonds connect the nets.

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