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Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)]
In the title compound, [Co(C(2)H(2)N(3))(C(7)H(4)NO(4))](n), the Co(II) atom is five-coordinated by three triazolate ligands and one bidentate 3-nitrobenzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the Co(II) atoms, generating a two-dimensional net paralle...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968154/ https://www.ncbi.nlm.nih.gov/pubmed/21581750 http://dx.doi.org/10.1107/S1600536808043596 |
| _version_ | 1782189790062444544 |
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| author | Qi, Xu-Liang |
| author_facet | Qi, Xu-Liang |
| author_sort | Qi, Xu-Liang |
| collection | PubMed |
| description | In the title compound, [Co(C(2)H(2)N(3))(C(7)H(4)NO(4))](n), the Co(II) atom is five-coordinated by three triazolate ligands and one bidentate 3-nitrobenzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the Co(II) atoms, generating a two-dimensional net parallel to the ab plane, in which both the Co(II) atom and the triazolate ligand act as three-connected nodes. Two weak intermolecular C—H⋯O hydrogen bonds connect the nets. |
| format | Text |
| id | pubmed-2968154 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29681542010-12-30 Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] Qi, Xu-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(2)H(2)N(3))(C(7)H(4)NO(4))](n), the Co(II) atom is five-coordinated by three triazolate ligands and one bidentate 3-nitrobenzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the Co(II) atoms, generating a two-dimensional net parallel to the ab plane, in which both the Co(II) atom and the triazolate ligand act as three-connected nodes. Two weak intermolecular C—H⋯O hydrogen bonds connect the nets. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968154/ /pubmed/21581750 http://dx.doi.org/10.1107/S1600536808043596 Text en © Xu-Liang Qi 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Qi, Xu-Liang Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] |
| title | Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] |
| title_full | Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] |
| title_fullStr | Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] |
| title_full_unstemmed | Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] |
| title_short | Poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(II)] |
| title_sort | poly[(3-nitrobenzoato)(μ(3)-1,2,4-triazolato)cobalt(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968154/ https://www.ncbi.nlm.nih.gov/pubmed/21581750 http://dx.doi.org/10.1107/S1600536808043596 |
| work_keys_str_mv | AT qixuliang poly3nitrobenzoatom3124triazolatocobaltii |