Cargando…

[μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate

The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo­condensation between N,N′-bis­(2-fur­yl)-N,N′-bis­(3-formyl-5-chloro­salicylaldehyde)ethyl­enediamine and 1,3-diamino­propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Chen, Cheng, Yu, Liu, Pan, Zhou, Hong, Pan, Zhi-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968155/
https://www.ncbi.nlm.nih.gov/pubmed/21581772
http://dx.doi.org/10.1107/S1600536809000166
Descripción
Sumario:The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo­condensation between N,N′-bis­(2-fur­yl)-N,N′-bis­(3-formyl-5-chloro­salicylaldehyde)ethyl­enediamine and 1,3-diamino­propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. The coordination geometry for each Cu(II) atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu⋯Cu distance of 3.0274 (9) Å.