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[μ-10,22-Dichloro-3,6-bis(2-furylmethyl)-3,6,14,18-tetraazatricyclo[18.3.1.1(8,12)]pentacosa-1(23),8,10,12(25),13,18,20(24),21-octaene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis[chloridocopper(II)] acetonitrile solvate
The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclocondensation between N,N′-bis(2-furyl)-N,N′-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine and 1,3-diaminopropane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. T...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968155/ https://www.ncbi.nlm.nih.gov/pubmed/21581772 http://dx.doi.org/10.1107/S1600536809000166 |
Sumario: | The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclocondensation between N,N′-bis(2-furyl)-N,N′-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine and 1,3-diaminopropane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. The coordination geometry for each Cu(II) atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu⋯Cu distance of 3.0274 (9) Å. |
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