[μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate

The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo­condensation between N,N′-bis­(2-fur­yl)-N,N′-bis­(3-formyl-5-chloro­salicylaldehyde)ethyl­enediamine and 1,3-diamino­propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. T...

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Detalles Bibliográficos
Autores principales: Chen, Chen, Cheng, Yu, Liu, Pan, Zhou, Hong, Pan, Zhi-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968155/
https://www.ncbi.nlm.nih.gov/pubmed/21581772
http://dx.doi.org/10.1107/S1600536809000166
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author Chen, Chen
Cheng, Yu
Liu, Pan
Zhou, Hong
Pan, Zhi-Quan
author_facet Chen, Chen
Cheng, Yu
Liu, Pan
Zhou, Hong
Pan, Zhi-Quan
author_sort Chen, Chen
collection PubMed
description The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo­condensation between N,N′-bis­(2-fur­yl)-N,N′-bis­(3-formyl-5-chloro­salicylaldehyde)ethyl­enediamine and 1,3-diamino­propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. The coordination geometry for each Cu(II) atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu⋯Cu distance of 3.0274 (9) Å.
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spelling pubmed-29681552010-12-30 [μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate Chen, Chen Cheng, Yu Liu, Pan Zhou, Hong Pan, Zhi-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo­condensation between N,N′-bis­(2-fur­yl)-N,N′-bis­(3-formyl-5-chloro­salicylaldehyde)ethyl­enediamine and 1,3-diamino­propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. The coordination geometry for each Cu(II) atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu⋯Cu distance of 3.0274 (9) Å. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968155/ /pubmed/21581772 http://dx.doi.org/10.1107/S1600536809000166 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Chen
Cheng, Yu
Liu, Pan
Zhou, Hong
Pan, Zhi-Quan
[μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate
title [μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate
title_full [μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate
title_fullStr [μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate
title_full_unstemmed [μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate
title_short [μ-10,22-Dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) N (3),N (6),O (24),O (25):N (14),N (18),O (24):O (25)]bis­[chloridocopper(II)] acetonitrile solvate
title_sort [μ-10,22-dichloro-3,6-bis­(2-furylmeth­yl)-3,6,14,18-tetra­azatricyclo­[18.3.1.1(8,12)]penta­cosa-1(23),8,10,12(25),13,18,20(24),21-octa­ene-24,25-diolato-κ(8) n (3),n (6),o (24),o (25):n (14),n (18),o (24):o (25)]bis­[chloridocopper(ii)] acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968155/
https://www.ncbi.nlm.nih.gov/pubmed/21581772
http://dx.doi.org/10.1107/S1600536809000166
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