Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate

The water-coordinated metal centre in the title salt, [Zn(C(12)H(8)N(2))(2)(H(2)O)(2)]C(7)H(4)O(6)S·4H(2)O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa­hedral environment. The cation, dianion and solvent water mol­ecules inter­act by O—H⋯O hydrogen bonds to...

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Detalles Bibliográficos
Autores principales: Zhang, Kou-Lin, Yang, Bo, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968159/
https://www.ncbi.nlm.nih.gov/pubmed/21581829
http://dx.doi.org/10.1107/S1600536809003055
Descripción
Sumario:The water-coordinated metal centre in the title salt, [Zn(C(12)H(8)N(2))(2)(H(2)O)(2)]C(7)H(4)O(6)S·4H(2)O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa­hedral environment. The cation, dianion and solvent water mol­ecules inter­act by O—H⋯O hydrogen bonds to form a layer motif. The SO(3) group is disordered over two positions with respect to the O atoms in a 0.76 (1):0.24 (1) ratio. One of the solvent water molecules is also disordered over two positions in a 0.56 (4):0.44 (4) ratio.

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