Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate

The water-coordinated metal centre in the title salt, [Zn(C(12)H(8)N(2))(2)(H(2)O)(2)]C(7)H(4)O(6)S·4H(2)O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa­hedral environment. The cation, dianion and solvent water mol­ecules inter­act by O—H⋯O hydrogen bonds to...

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Detalles Bibliográficos
Autores principales: Zhang, Kou-Lin, Yang, Bo, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968159/
https://www.ncbi.nlm.nih.gov/pubmed/21581829
http://dx.doi.org/10.1107/S1600536809003055
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author Zhang, Kou-Lin
Yang, Bo
Ng, Seik Weng
author_facet Zhang, Kou-Lin
Yang, Bo
Ng, Seik Weng
author_sort Zhang, Kou-Lin
collection PubMed
description The water-coordinated metal centre in the title salt, [Zn(C(12)H(8)N(2))(2)(H(2)O)(2)]C(7)H(4)O(6)S·4H(2)O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa­hedral environment. The cation, dianion and solvent water mol­ecules inter­act by O—H⋯O hydrogen bonds to form a layer motif. The SO(3) group is disordered over two positions with respect to the O atoms in a 0.76 (1):0.24 (1) ratio. One of the solvent water molecules is also disordered over two positions in a 0.56 (4):0.44 (4) ratio.
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spelling pubmed-29681592010-12-30 Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate Zhang, Kou-Lin Yang, Bo Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The water-coordinated metal centre in the title salt, [Zn(C(12)H(8)N(2))(2)(H(2)O)(2)]C(7)H(4)O(6)S·4H(2)O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa­hedral environment. The cation, dianion and solvent water mol­ecules inter­act by O—H⋯O hydrogen bonds to form a layer motif. The SO(3) group is disordered over two positions with respect to the O atoms in a 0.76 (1):0.24 (1) ratio. One of the solvent water molecules is also disordered over two positions in a 0.56 (4):0.44 (4) ratio. International Union of Crystallography 2009-01-31 /pmc/articles/PMC2968159/ /pubmed/21581829 http://dx.doi.org/10.1107/S1600536809003055 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Kou-Lin
Yang, Bo
Ng, Seik Weng
Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
title Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
title_full Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
title_fullStr Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
title_full_unstemmed Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
title_short Diaqua­bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
title_sort diaqua­bis(1,10-phenanthroline-κ(2) n,n′)zinc(ii) 2-hydr­oxy-5-sulfonatobenzoate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968159/
https://www.ncbi.nlm.nih.gov/pubmed/21581829
http://dx.doi.org/10.1107/S1600536809003055
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AT ngseikweng diaquabis110phenanthrolinek2nnzincii2hydroxy5sulfonatobenzoatetetrahydrate

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