Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate

In the title compound, [Ag(C(6)H(5)NO(2))(2)]ClO(4), the Ag(I) atom shows an almost linear coordination geometry, defined by two N atoms from two pyridine-3-carboxylic acid ligands. The complex cations are linked by hydrogen bonds between the carboxyl groups into a chain. The chains are further conn...

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Detalles Bibliográficos
Autores principales: Nie, Xiao-Yan, Li, Qian-Zhu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968163/
https://www.ncbi.nlm.nih.gov/pubmed/21581761
http://dx.doi.org/10.1107/S1600536808044206
Descripción
Sumario:In the title compound, [Ag(C(6)H(5)NO(2))(2)]ClO(4), the Ag(I) atom shows an almost linear coordination geometry, defined by two N atoms from two pyridine-3-carboxylic acid ligands. The complex cations are linked by hydrogen bonds between the carboxyl groups into a chain. The chains are further connected through C—H⋯O hydrogen bonds and a weak Ag⋯O inter­action [2.757 (8) Å] into a layer. Another Ag⋯O inter­action [2.899 (2) Å] and a C—H⋯O hydrogen bond connect the layers into a three-dimensional network.

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