Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate

In the title compound, [Ag(C(6)H(5)NO(2))(2)]ClO(4), the Ag(I) atom shows an almost linear coordination geometry, defined by two N atoms from two pyridine-3-carboxylic acid ligands. The complex cations are linked by hydrogen bonds between the carboxyl groups into a chain. The chains are further conn...

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Detalles Bibliográficos
Autores principales: Nie, Xiao-Yan, Li, Qian-Zhu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968163/
https://www.ncbi.nlm.nih.gov/pubmed/21581761
http://dx.doi.org/10.1107/S1600536808044206
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author Nie, Xiao-Yan
Li, Qian-Zhu
author_facet Nie, Xiao-Yan
Li, Qian-Zhu
author_sort Nie, Xiao-Yan
collection PubMed
description In the title compound, [Ag(C(6)H(5)NO(2))(2)]ClO(4), the Ag(I) atom shows an almost linear coordination geometry, defined by two N atoms from two pyridine-3-carboxylic acid ligands. The complex cations are linked by hydrogen bonds between the carboxyl groups into a chain. The chains are further connected through C—H⋯O hydrogen bonds and a weak Ag⋯O inter­action [2.757 (8) Å] into a layer. Another Ag⋯O inter­action [2.899 (2) Å] and a C—H⋯O hydrogen bond connect the layers into a three-dimensional network.
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spelling pubmed-29681632010-12-30 Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate Nie, Xiao-Yan Li, Qian-Zhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(6)H(5)NO(2))(2)]ClO(4), the Ag(I) atom shows an almost linear coordination geometry, defined by two N atoms from two pyridine-3-carboxylic acid ligands. The complex cations are linked by hydrogen bonds between the carboxyl groups into a chain. The chains are further connected through C—H⋯O hydrogen bonds and a weak Ag⋯O inter­action [2.757 (8) Å] into a layer. Another Ag⋯O inter­action [2.899 (2) Å] and a C—H⋯O hydrogen bond connect the layers into a three-dimensional network. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968163/ /pubmed/21581761 http://dx.doi.org/10.1107/S1600536808044206 Text en © Nie and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nie, Xiao-Yan
Li, Qian-Zhu
Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate
title Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate
title_full Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate
title_fullStr Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate
title_full_unstemmed Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate
title_short Bis(pyridine-3-carboxylic acid-κN)silver(I) perchlorate
title_sort bis(pyridine-3-carboxylic acid-κn)silver(i) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968163/
https://www.ncbi.nlm.nih.gov/pubmed/21581761
http://dx.doi.org/10.1107/S1600536808044206
work_keys_str_mv AT niexiaoyan bispyridine3carboxylicacidknsilveriperchlorate
AT liqianzhu bispyridine3carboxylicacidknsilveriperchlorate

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