Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate

The title compound, [Ni(2)(C(12)H(12)N(2)O(4)S(3))(H(2)O)(4)]·2C(3)H(7)NO·3H(2)O, is made up of a centrosymmetric, bimetallic complex containing a 24-membered macrocyclic ring, two dimethyl­formamide and three water solvent mol­ecules. The Ni atom adopts a slightly distorted NiO(6) octahedral geomet...

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Detalles Bibliográficos
Autores principales: Jian, Fang-Fang, Han, Song-Jiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968170/
https://www.ncbi.nlm.nih.gov/pubmed/21581804
http://dx.doi.org/10.1107/S1600536808043699
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author Jian, Fang-Fang
Han, Song-Jiang
author_facet Jian, Fang-Fang
Han, Song-Jiang
author_sort Jian, Fang-Fang
collection PubMed
description The title compound, [Ni(2)(C(12)H(12)N(2)O(4)S(3))(H(2)O)(4)]·2C(3)H(7)NO·3H(2)O, is made up of a centrosymmetric, bimetallic complex containing a 24-membered macrocyclic ring, two dimethyl­formamide and three water solvent mol­ecules. The Ni atom adopts a slightly distorted NiO(6) octahedral geometry arising from two O,O-bidentate ligands and two water molecules. There are inter­molecular O—H⋯O and O—H⋯N inter­actions in the crystal structure. One of the uncoordinated water molecules is diordered over two sets of sites of equal occupancy.
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spelling pubmed-29681702010-12-30 Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate Jian, Fang-Fang Han, Song-Jiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(2)(C(12)H(12)N(2)O(4)S(3))(H(2)O)(4)]·2C(3)H(7)NO·3H(2)O, is made up of a centrosymmetric, bimetallic complex containing a 24-membered macrocyclic ring, two dimethyl­formamide and three water solvent mol­ecules. The Ni atom adopts a slightly distorted NiO(6) octahedral geometry arising from two O,O-bidentate ligands and two water molecules. There are inter­molecular O—H⋯O and O—H⋯N inter­actions in the crystal structure. One of the uncoordinated water molecules is diordered over two sets of sites of equal occupancy. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968170/ /pubmed/21581804 http://dx.doi.org/10.1107/S1600536808043699 Text en © Jian and Han 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jian, Fang-Fang
Han, Song-Jiang
Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate
title Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate
title_full Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate
title_fullStr Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate
title_full_unstemmed Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate
title_short Bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(II)] dimethyl­formamide disolvate trihydrate
title_sort bis­{μ-3,3′-(1,3,4-thia­diazole-2,5-diyl­dithio)bis­[penta­ne­dionato(1−)]}bis­[diaqua­nickel(ii)] dimethyl­formamide disolvate trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968170/
https://www.ncbi.nlm.nih.gov/pubmed/21581804
http://dx.doi.org/10.1107/S1600536808043699
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AT hansongjiang bism33134thiadiazole25diyldithiobispentanedionato1bisdiaquanickeliidimethylformamidedisolvatetrihydrate

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