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(3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)

The title compound, [Ag(C(7)H(2)Br(3)O(2))(C(18)H(15)P)(3)], a silver(I) derivative of 3,5,7-tribromo­tropolone, has three triphenyl­phosphine ligands coordinated to the silver centre, whereas the 3,5,7-tribromo­tropolonate anion coordinates as a bidentate ligand. The compound is an example of a fiv...

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Detalles Bibliográficos
Autores principales: Steyl, G., Hill, T. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968179/
https://www.ncbi.nlm.nih.gov/pubmed/21581792
http://dx.doi.org/10.1107/S1600536809000890
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author Steyl, G.
Hill, T. N.
author_facet Steyl, G.
Hill, T. N.
author_sort Steyl, G.
collection PubMed
description The title compound, [Ag(C(7)H(2)Br(3)O(2))(C(18)H(15)P)(3)], a silver(I) derivative of 3,5,7-tribromo­tropolone, has three triphenyl­phosphine ligands coordinated to the silver centre, whereas the 3,5,7-tribromo­tropolonate anion coordinates as a bidentate ligand. The compound is an example of a five-coordinate silver complex containing a bidentate ligand.
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spelling pubmed-29681792010-12-30 (3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I) Steyl, G. Hill, T. N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(C(7)H(2)Br(3)O(2))(C(18)H(15)P)(3)], a silver(I) derivative of 3,5,7-tribromo­tropolone, has three triphenyl­phosphine ligands coordinated to the silver centre, whereas the 3,5,7-tribromo­tropolonate anion coordinates as a bidentate ligand. The compound is an example of a five-coordinate silver complex containing a bidentate ligand. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968179/ /pubmed/21581792 http://dx.doi.org/10.1107/S1600536809000890 Text en © Steyl and Hill 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Steyl, G.
Hill, T. N.
(3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)
title (3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)
title_full (3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)
title_fullStr (3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)
title_full_unstemmed (3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)
title_short (3,5,7-Tribromo­tropolonato-κ(2) O,O′)tris­(triphenyl­phosphine-κP)silver(I)
title_sort (3,5,7-tribromo­tropolonato-κ(2) o,o′)tris­(triphenyl­phosphine-κp)silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968179/
https://www.ncbi.nlm.nih.gov/pubmed/21581792
http://dx.doi.org/10.1107/S1600536809000890
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