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La variété β-NaMoO(2)(AsO(4))
The title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO(2)AsO(4), was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO(4) tetrahedra and MoO(6) octahedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968181/ https://www.ncbi.nlm.nih.gov/pubmed/21581739 http://dx.doi.org/10.1107/S1600536809002517 |
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author | Ben Hlila, Soumaya Zid, Mohamed Faouzi Driss, Ahmed |
author_facet | Ben Hlila, Soumaya Zid, Mohamed Faouzi Driss, Ahmed |
author_sort | Ben Hlila, Soumaya |
collection | PubMed |
description | The title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO(2)AsO(4), was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO(4) tetrahedra and MoO(6) octahedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities parallel to [010] where disordered six-coordinated sodium cations (half-occupation) are located. Structural relationships between the different orthoarsenates of the AMoO(2)AsO(4) series (A = Ag, Li, Na, K and Rb) are discussed. |
format | Text |
id | pubmed-2968181 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681812010-12-30 La variété β-NaMoO(2)(AsO(4)) Ben Hlila, Soumaya Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO(2)AsO(4), was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO(4) tetrahedra and MoO(6) octahedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities parallel to [010] where disordered six-coordinated sodium cations (half-occupation) are located. Structural relationships between the different orthoarsenates of the AMoO(2)AsO(4) series (A = Ag, Li, Na, K and Rb) are discussed. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968181/ /pubmed/21581739 http://dx.doi.org/10.1107/S1600536809002517 Text en © Ben Hlila et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Ben Hlila, Soumaya Zid, Mohamed Faouzi Driss, Ahmed La variété β-NaMoO(2)(AsO(4)) |
title | La variété β-NaMoO(2)(AsO(4)) |
title_full | La variété β-NaMoO(2)(AsO(4)) |
title_fullStr | La variété β-NaMoO(2)(AsO(4)) |
title_full_unstemmed | La variété β-NaMoO(2)(AsO(4)) |
title_short | La variété β-NaMoO(2)(AsO(4)) |
title_sort | la variété β-namoo(2)(aso(4)) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968181/ https://www.ncbi.nlm.nih.gov/pubmed/21581739 http://dx.doi.org/10.1107/S1600536809002517 |
work_keys_str_mv | AT benhlilasoumaya lavarietebnamoo2aso4 AT zidmohamedfaouzi lavarietebnamoo2aso4 AT drissahmed lavarietebnamoo2aso4 |