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rac-Methyl 4-azido-3-hydr­oxy-3-(2-nitro­phen­yl)butanoate

In the title compound, C(11)H(12)N(4)O(5), the mean plane through the nitro substituent on the benzene ring is inclined to the benzene mean plane by 85.8 (2)°, which avoids steric inter­actions with the ortho substituents. The hydr­oxy group is involved in bifurcated hydrogen bonds. The first is an...

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Detalles Bibliográficos
Autores principales: Vallat, Olivier, Buciumas, Ana-Maria, Neier, Reinhard, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968186/
https://www.ncbi.nlm.nih.gov/pubmed/21581990
http://dx.doi.org/10.1107/S1600536808043857
Descripción
Sumario:In the title compound, C(11)H(12)N(4)O(5), the mean plane through the nitro substituent on the benzene ring is inclined to the benzene mean plane by 85.8 (2)°, which avoids steric inter­actions with the ortho substituents. The hydr­oxy group is involved in bifurcated hydrogen bonds. The first is an intra­molecular O—H⋯O hydrogen bond, involving the ester carbonyl O atom, which gives rise to the formation of a boat-like hydrogen-bonded chelate ring. The second is an inter­molecular O—H⋯N hydrogen bond involving the first N atom of the azide group of a symmetry-related mol­ecule. In the crystal structure this leads to the formation of a polmer chain extending in the c-axis direction.