Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate

The title compound, 2C(21)H(34)N(4)O(3)S(2+)·4I(−)·5H(2)O, was prepared exclusively as the E isomer by methyl­ation of the corresponding N-phenyl­pyridin-4-amine. There are two symmetry-independent mol­ecules in the asymmetric unit with no significant differences in bond lengths and angles. The arom...

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Detalles Bibliográficos
Autores principales: Rodrigues, Tiago, Moreira, Rui, Dacunha-Marinho, Bruno, Lopes, Francisca
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968188/
https://www.ncbi.nlm.nih.gov/pubmed/21581896
http://dx.doi.org/10.1107/S1600536809000324
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author Rodrigues, Tiago
Moreira, Rui
Dacunha-Marinho, Bruno
Lopes, Francisca
author_facet Rodrigues, Tiago
Moreira, Rui
Dacunha-Marinho, Bruno
Lopes, Francisca
author_sort Rodrigues, Tiago
collection PubMed
description The title compound, 2C(21)H(34)N(4)O(3)S(2+)·4I(−)·5H(2)O, was prepared exclusively as the E isomer by methyl­ation of the corresponding N-phenyl­pyridin-4-amine. There are two symmetry-independent mol­ecules in the asymmetric unit with no significant differences in bond lengths and angles. The aromatic rings are not coplanar with the pyridin-4-imine groups, as indicated by the C—N—C—C torsion angles of 47.7 (7) and 132.6 (5)°.
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spelling pubmed-29681882010-12-30 Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate Rodrigues, Tiago Moreira, Rui Dacunha-Marinho, Bruno Lopes, Francisca Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 2C(21)H(34)N(4)O(3)S(2+)·4I(−)·5H(2)O, was prepared exclusively as the E isomer by methyl­ation of the corresponding N-phenyl­pyridin-4-amine. There are two symmetry-independent mol­ecules in the asymmetric unit with no significant differences in bond lengths and angles. The aromatic rings are not coplanar with the pyridin-4-imine groups, as indicated by the C—N—C—C torsion angles of 47.7 (7) and 132.6 (5)°. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968188/ /pubmed/21581896 http://dx.doi.org/10.1107/S1600536809000324 Text en © Rodrigues et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Tiago
Moreira, Rui
Dacunha-Marinho, Bruno
Lopes, Francisca
Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
title Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
title_full Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
title_fullStr Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
title_full_unstemmed Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
title_short Bis{(E)-3-[(diethyl­methyl­ammonio)meth­yl]-N-[3-(N,N-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
title_sort bis{(e)-3-[(diethyl­methyl­ammonio)meth­yl]-n-[3-(n,n-dimethyl­sulfamo­yl)-1-methyl­pyridin-4-yl­idene]-4-methoxy­anilinium} tetra­iodide penta­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968188/
https://www.ncbi.nlm.nih.gov/pubmed/21581896
http://dx.doi.org/10.1107/S1600536809000324
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