Dichlorido(dipyrido[3,2-a:2′,3′-c]phenazine)manganese(II)

The complete mol­ecule of the title compound, [MnCl(2)(C(18)H(10)N(4))(2)], is generated by crystallographic twofold symmetry with the Mn atom lying on the rotation axis. The Mn coordination geometry is a distorted cis-MnCl(2)N(4) octa­hedron, arising from two N,N′-bidentate dipyrido[3,2-a:2′,3′-c]p...

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Detalles Bibliográficos
Autores principales: Xu, Mao-Liang, Sun, Shu-Bo, Li, Xiu-Ying, Che, Guang-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968193/
https://www.ncbi.nlm.nih.gov/pubmed/21581752
http://dx.doi.org/10.1107/S1600536808043468
Descripción
Sumario:The complete mol­ecule of the title compound, [MnCl(2)(C(18)H(10)N(4))(2)], is generated by crystallographic twofold symmetry with the Mn atom lying on the rotation axis. The Mn coordination geometry is a distorted cis-MnCl(2)N(4) octa­hedron, arising from two N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine (DPPZ) ligands and two chloride ions. In the crystal structure, neighbouring mononuclear units pack together through π–π contacts between the DPPZ rings [shortest centroid–centroid distance = 3.480 (2) Å], leading to a chain-like structure along [001]. C—H⋯Cl hydrogen bonds complete the structure.

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