Cargando…

1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate

The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea mol­ecules and two trichloro­methane mol­ecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical t...

Descripción completa

Detalles Bibliográficos
Autores principales: Khawar Rauf, M., Bolte, Michael, Anwar, Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968195/
https://www.ncbi.nlm.nih.gov/pubmed/21581865
http://dx.doi.org/10.1107/S1600536809000051
Descripción
Sumario:The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea mol­ecules and two trichloro­methane mol­ecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical thio­urea C—S and C—O bonds lengths, as well as shortened C—N bonds. The —NH—C(=S)—NH—C(=O)— plane is almost perpen­dicular to the benzene ring in each thiourea molecule. Intra­molecular N—H⋯O hydrogen bonds stabilize the mol­ecular conformation and inter­molecular N—H⋯S hydrogen bonds stabilize the packing arrangement.