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1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate
The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea molecules and two trichloromethane molecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical t...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968195/ https://www.ncbi.nlm.nih.gov/pubmed/21581865 http://dx.doi.org/10.1107/S1600536809000051 |
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author | Khawar Rauf, M. Bolte, Michael Anwar, Saeed |
author_facet | Khawar Rauf, M. Bolte, Michael Anwar, Saeed |
author_sort | Khawar Rauf, M. |
collection | PubMed |
description | The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea molecules and two trichloromethane molecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical thiourea C—S and C—O bonds lengths, as well as shortened C—N bonds. The —NH—C(=S)—NH—C(=O)— plane is almost perpendicular to the benzene ring in each thiourea molecule. Intramolecular N—H⋯O hydrogen bonds stabilize the molecular conformation and intermolecular N—H⋯S hydrogen bonds stabilize the packing arrangement. |
format | Text |
id | pubmed-2968195 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29681952010-12-30 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate Khawar Rauf, M. Bolte, Michael Anwar, Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea molecules and two trichloromethane molecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical thiourea C—S and C—O bonds lengths, as well as shortened C—N bonds. The —NH—C(=S)—NH—C(=O)— plane is almost perpendicular to the benzene ring in each thiourea molecule. Intramolecular N—H⋯O hydrogen bonds stabilize the molecular conformation and intermolecular N—H⋯S hydrogen bonds stabilize the packing arrangement. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968195/ /pubmed/21581865 http://dx.doi.org/10.1107/S1600536809000051 Text en © Khawar Rauf et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Khawar Rauf, M. Bolte, Michael Anwar, Saeed 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
title | 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
title_full | 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
title_fullStr | 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
title_full_unstemmed | 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
title_short | 1-(2,6-Dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
title_sort | 1-(2,6-dichlorobenzoyl)-3-(2,3,5,6-tetrachlorophenyl)thiourea trichloromethane hemisolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968195/ https://www.ncbi.nlm.nih.gov/pubmed/21581865 http://dx.doi.org/10.1107/S1600536809000051 |
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