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1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate

The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea mol­ecules and two trichloro­methane mol­ecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical t...

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Detalles Bibliográficos
Autores principales: Khawar Rauf, M., Bolte, Michael, Anwar, Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968195/
https://www.ncbi.nlm.nih.gov/pubmed/21581865
http://dx.doi.org/10.1107/S1600536809000051
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author Khawar Rauf, M.
Bolte, Michael
Anwar, Saeed
author_facet Khawar Rauf, M.
Bolte, Michael
Anwar, Saeed
author_sort Khawar Rauf, M.
collection PubMed
description The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea mol­ecules and two trichloro­methane mol­ecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical thio­urea C—S and C—O bonds lengths, as well as shortened C—N bonds. The —NH—C(=S)—NH—C(=O)— plane is almost perpen­dicular to the benzene ring in each thiourea molecule. Intra­molecular N—H⋯O hydrogen bonds stabilize the mol­ecular conformation and inter­molecular N—H⋯S hydrogen bonds stabilize the packing arrangement.
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spelling pubmed-29681952010-12-30 1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate Khawar Rauf, M. Bolte, Michael Anwar, Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(6)Cl(6)N(2)OS·0.5CHCl(3), crystallizes with four 1-(2,6-dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea mol­ecules and two trichloro­methane mol­ecules in the asymmetric unit. The thiourea molecules exist in the solid state in their thione forms with typical thio­urea C—S and C—O bonds lengths, as well as shortened C—N bonds. The —NH—C(=S)—NH—C(=O)— plane is almost perpen­dicular to the benzene ring in each thiourea molecule. Intra­molecular N—H⋯O hydrogen bonds stabilize the mol­ecular conformation and inter­molecular N—H⋯S hydrogen bonds stabilize the packing arrangement. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968195/ /pubmed/21581865 http://dx.doi.org/10.1107/S1600536809000051 Text en © Khawar Rauf et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khawar Rauf, M.
Bolte, Michael
Anwar, Saeed
1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
title 1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
title_full 1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
title_fullStr 1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
title_full_unstemmed 1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
title_short 1-(2,6-Dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
title_sort 1-(2,6-dichloro­benzo­yl)-3-(2,3,5,6-tetra­chloro­phen­yl)thio­urea trichloro­methane hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968195/
https://www.ncbi.nlm.nih.gov/pubmed/21581865
http://dx.doi.org/10.1107/S1600536809000051
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AT anwarsaeed 126dichlorobenzoyl32356tetrachlorophenylthioureatrichloromethanehemisolvate